ALINITY DETERMINATION IN WATER BY MOHR METHOD Most precipitation titration uses standard silver nitrate solution as titrant. Mohr method is one example of Argentometric titration method, the other two are Fajans and Volhard methods. It uses CrO42- as indicator in the titration of chloride ion with silver nitrate. In any solution containing chloride and chromate ions, the chloride ions are precipitated by silver ion first before the chromate ion. In this exercise, salinity of natural water will be based upon the chlorinity of the sample. Salinity is a measure of the salt content of seawater. It is directly proportional to the amount of chloride ion in water, and is computed as: S (ppt) = 1.805 [ppt Cl−] + 0.03 QUESTIONS 1: Why should the pH of the water sample be adjusted to 7-8? 2: Does the value for the salinity correspond to the type of water sample used in the exercise (i.e.
Ionic Equilibrium
Chemical equilibrium and ionic equilibrium are two major concepts in chemistry. Ionic equilibrium deals with the equilibrium involved in an ionization process while chemical equilibrium deals with the equilibrium during a chemical change. Ionic equilibrium is established between the ions and unionized species in a system. Understanding the concept of ionic equilibrium is very important to answer the questions related to certain chemical reactions in chemistry.
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Bronsted-Lowry base in inorganic chemistry is any chemical substance that can accept a proton from the other chemical substance it is reacting with.
ALINITY DETERMINATION IN WATER BY MOHR METHOD
Most precipitation titration uses standard silver nitrate solution as titrant. Mohr method is one example of Argentometric titration method, the other two are Fajans and Volhard methods. It uses CrO42- as indicator in the titration of chloride ion with silver nitrate. In any solution containing chloride and chromate ions, the chloride ions are precipitated by silver ion first before the chromate ion. In this exercise, salinity of natural water will be based upon the chlorinity of the sample. Salinity is a measure of the salt content of seawater. It is directly proportional to the amount of chloride ion in water, and is computed as: S (ppt) = 1.805 [ppt Cl−] + 0.03
QUESTIONS
1: Why should the pH of the water sample be adjusted to 7-8?
2: Does the value for the salinity correspond to the type of water sample used in the exercise (i.e., seawater)?
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