Alcohol is removed from the blood in a two-step oxidation to acetate ion. Unfortunately, the first step produces the toxic compound acetaldehyde. This oxidation is catalyzed by the enzyme liver alcohol dehydrogenase (LAD). This is represented by the following equation: LAD 2C2H6O(l) + O2(g)2C2H4O(1) + 2H2O(1) The standard entropy and enthalpy of formation of each species is given in the following table: Standard Entropy and Enthalpy of Formation of Each Species C2H6O O2 C2H4O H₂O H₁° -277.7 0 -192.3 -285.8 (kJ/mol) Sº (J/mol*K) 160.7 205.1 160.2 69.9 a. Calculate AH° and AS° for the reaction. b. Calculate AGº at 25 °C c. Calculate K for the reaction
Alcohol is removed from the blood in a two-step oxidation to acetate ion. Unfortunately, the first step produces the toxic compound acetaldehyde. This oxidation is catalyzed by the enzyme liver alcohol dehydrogenase (LAD). This is represented by the following equation: LAD 2C2H6O(l) + O2(g)2C2H4O(1) + 2H2O(1) The standard entropy and enthalpy of formation of each species is given in the following table: Standard Entropy and Enthalpy of Formation of Each Species C2H6O O2 C2H4O H₂O H₁° -277.7 0 -192.3 -285.8 (kJ/mol) Sº (J/mol*K) 160.7 205.1 160.2 69.9 a. Calculate AH° and AS° for the reaction. b. Calculate AGº at 25 °C c. Calculate K for the reaction
Chemistry
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ISBN:9781305957404
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Chapter1: Chemical Foundations
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![Alcohol is removed from the blood in a two-step oxidation to
acetate ion. Unfortunately, the first step produces the toxic
compound acetaldehyde. This oxidation is catalyzed by the
enzyme liver alcohol dehydrogenase (LAD). This is represented
by the following equation:
LAD
2C2H6O(l) + O2(g)2C2H4O(1) + 2H2O(1)
The standard entropy and enthalpy of formation of each species
is given in the following table:
Standard Entropy and Enthalpy of
Formation of Each Species
C2H6O O2 C2H4O H₂O
H₁°
-277.7 0 -192.3 -285.8
(kJ/mol)
Sº
(J/mol*K)
160.7 205.1 160.2 69.9
a. Calculate AH° and AS° for the reaction.
b. Calculate AGº at 25 °C
c. Calculate K for the reaction](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9403bc08-39e0-4b6f-a7fd-dc90255e1e29%2Fe9b56ca9-2b4f-4a54-9e68-03c0abd293f5%2Fvaus7k_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Alcohol is removed from the blood in a two-step oxidation to
acetate ion. Unfortunately, the first step produces the toxic
compound acetaldehyde. This oxidation is catalyzed by the
enzyme liver alcohol dehydrogenase (LAD). This is represented
by the following equation:
LAD
2C2H6O(l) + O2(g)2C2H4O(1) + 2H2O(1)
The standard entropy and enthalpy of formation of each species
is given in the following table:
Standard Entropy and Enthalpy of
Formation of Each Species
C2H6O O2 C2H4O H₂O
H₁°
-277.7 0 -192.3 -285.8
(kJ/mol)
Sº
(J/mol*K)
160.7 205.1 160.2 69.9
a. Calculate AH° and AS° for the reaction.
b. Calculate AGº at 25 °C
c. Calculate K for the reaction
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