Ag/A9CI is a commonly used reference electrode in a laboratory, which can be represented as Ag/AgCl /XM KCI. The potential of this electrode is governed by the Nernst equation. Based on the following standard reduction potential (Eº) and Ksp Values (T = 25 °C), Ag* + e' = Ag (E° = 0.799 V vs SHE) AgCl = Ag* + CI (Ksp = 1.77 x 10ʻ1º) (a) Calculate the E° value for the Ag/AgCl reference electrode. E° = V (b) If the concentration of the internal filling KCI solution for the Ag/AgCl electrode is 3 M, calculate the potential of this reference electrode.

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Ag/AgCl is a commonly used reference electrode in a laboratory, which can be represented as Ag/AgCl
/XM KCI. The potential of this electrode is governed by the Nernst equation.
Based on the following standard reduction potential (Eº) and Ksp Vvalues (T = 25 °C),
Ag* + e° = Ag
(E° = 0.799 V vs SHE)
AgCI = Ag* + Clr
(Ksp = 1.77 x 10ʻ10)
(a) Calculate the E° value for the Ag/AgCl reference electrode.
E° =
V
(b) If the concentration of the internal filling KCI solution for the Ag/AgCl electrode is 3 M, calculate the
potential of this reference electrode.
E =
(c) The Eº value for the Cd2+ + 2e* = Cd process is -0.403 V versus the SHE. What is the E value for this
process if a Ag/AgCl/3M KCI electrode is used as the reference electrode?
E° =
V
Transcribed Image Text:Ag/AgCl is a commonly used reference electrode in a laboratory, which can be represented as Ag/AgCl /XM KCI. The potential of this electrode is governed by the Nernst equation. Based on the following standard reduction potential (Eº) and Ksp Vvalues (T = 25 °C), Ag* + e° = Ag (E° = 0.799 V vs SHE) AgCI = Ag* + Clr (Ksp = 1.77 x 10ʻ10) (a) Calculate the E° value for the Ag/AgCl reference electrode. E° = V (b) If the concentration of the internal filling KCI solution for the Ag/AgCl electrode is 3 M, calculate the potential of this reference electrode. E = (c) The Eº value for the Cd2+ + 2e* = Cd process is -0.403 V versus the SHE. What is the E value for this process if a Ag/AgCl/3M KCI electrode is used as the reference electrode? E° = V
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