Additional Problem #3: The hydrolysis of ethylene oxide in the presence of H2SO4 catalyst to CH2CH20 + H2O → CH2OHCH2OH ethylene glycol: has been studied at 55°C by mixing 500 ml of a 2M solution of ethylene oxide in H2O with 500 ml of H20 containing 0.9 wt. % H2SO4. Note that H2SO4 is a catalyst and is NOT consumed during the reaction. Use the data below to determine the reaction order and the value of the rate constant. The reactor can be modeled as a batch reactor. (Note that the reaction was conducted in excess H20 and its concentration did not change.) Time (min) Concentration of Ethylene Glycol (mol/L) 0.000 0.0 0.145 0.5 0.270 1.0 0.376 1.5 0.467 2.0 0.610 3.0 0.715 4.0 0.848 6.0 0.957 10.0

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Additional Problem #3: The hydrolysis of ethylene oxide in the presence of H2SO4 catalyst to
CH2CH2O + H20 → CH2OHCH2OH
ethylene glycol:
has been studied at 55°C by mixing 500 ml of a 2M solution of ethylene oxide in H20 with 500
ml of H20 containing 0.9 wt. % H2SO4. Note that H2SO4 is a catalyst and is NOT consumed
during the reaction. Use the data below to determine the reaction order and the value of the
rate constant. The reactor can be modeled as a batch reactor. (Note that the reaction was
conducted in excess H2O and its concentration did not change.)
Time (min)
Concentration of Ethylene Glycol (mol/L)
0.000
0.0
0.145
0.5
0.270
1.0
0.376
1.5
0.467
2.0
0.610
3.0
0.715
4.0
0.848
6.0
0.957
10.0
Additional Problem #4: A convenient laboratory technique for determining the kinetics of gas
phase reactions involves using a constant volume isothermal vessel and measuring pressure
changes with time. The container can be modeled as a batch reactor. Use the data below to
Transcribed Image Text:- + 100% 7 of 8 Additional Problem #3: The hydrolysis of ethylene oxide in the presence of H2SO4 catalyst to CH2CH2O + H20 → CH2OHCH2OH ethylene glycol: has been studied at 55°C by mixing 500 ml of a 2M solution of ethylene oxide in H20 with 500 ml of H20 containing 0.9 wt. % H2SO4. Note that H2SO4 is a catalyst and is NOT consumed during the reaction. Use the data below to determine the reaction order and the value of the rate constant. The reactor can be modeled as a batch reactor. (Note that the reaction was conducted in excess H2O and its concentration did not change.) Time (min) Concentration of Ethylene Glycol (mol/L) 0.000 0.0 0.145 0.5 0.270 1.0 0.376 1.5 0.467 2.0 0.610 3.0 0.715 4.0 0.848 6.0 0.957 10.0 Additional Problem #4: A convenient laboratory technique for determining the kinetics of gas phase reactions involves using a constant volume isothermal vessel and measuring pressure changes with time. The container can be modeled as a batch reactor. Use the data below to
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