acid or a Lewis base. pective bins.

Chemistry
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Lewis Acids and Bases

By the Brønsted-Lowry definition, acids are proton donors and bases are proton acceptors. By the Lewis definition, acids are electron-pair acceptors, and bases are electron-pair donors. For bases, the two definitions are equivalent such that all Lewis bases are Brønsted-Lowry bases and vice versa.

However, it is possible to have a Lewis acid that is not a Brønsted-Lowry acid. This is because Lewis acids include molecules and cations that have a vacant valence orbital, regardless of whether they have a proton to donate.

Common examples of Lewis acids (that are not Brønsted-Lowry acids) are metal ions, such as Al³⁺ and Cu²⁺. The following is an example of a Lewis acid-base reaction:

\[ \text{Cu}^{2+} + 4\text{NH}_3 \rightarrow \text{Cu}(\text{NH}_3)_4^{2+} \]

\(\text{NH}_3\) donates the electron pair to \(\text{Cu}^{2+}\). Therefore, \(\text{NH}_3\) is a Lewis base, and \(\text{Cu}^{2+}\) is a Lewis acid.

### Part B

Classify each of the following as a Lewis acid or a Lewis base.

Drag the appropriate items to their respective bins.

- **Options:** CO₂, NH₃, SiCl₄, CH₃OH, Cl⁻, CN⁻, Mn²⁺
- **Bins:** Lewis acids, Lewis bases

Please note that this section involves interaction with the content, such as classifying each chemical species under the appropriate category of Lewis acids or bases based on their ability to accept or donate electron pairs.
Transcribed Image Text:### Lewis Acids and Bases By the Brønsted-Lowry definition, acids are proton donors and bases are proton acceptors. By the Lewis definition, acids are electron-pair acceptors, and bases are electron-pair donors. For bases, the two definitions are equivalent such that all Lewis bases are Brønsted-Lowry bases and vice versa. However, it is possible to have a Lewis acid that is not a Brønsted-Lowry acid. This is because Lewis acids include molecules and cations that have a vacant valence orbital, regardless of whether they have a proton to donate. Common examples of Lewis acids (that are not Brønsted-Lowry acids) are metal ions, such as Al³⁺ and Cu²⁺. The following is an example of a Lewis acid-base reaction: \[ \text{Cu}^{2+} + 4\text{NH}_3 \rightarrow \text{Cu}(\text{NH}_3)_4^{2+} \] \(\text{NH}_3\) donates the electron pair to \(\text{Cu}^{2+}\). Therefore, \(\text{NH}_3\) is a Lewis base, and \(\text{Cu}^{2+}\) is a Lewis acid. ### Part B Classify each of the following as a Lewis acid or a Lewis base. Drag the appropriate items to their respective bins. - **Options:** CO₂, NH₃, SiCl₄, CH₃OH, Cl⁻, CN⁻, Mn²⁺ - **Bins:** Lewis acids, Lewis bases Please note that this section involves interaction with the content, such as classifying each chemical species under the appropriate category of Lewis acids or bases based on their ability to accept or donate electron pairs.
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