Acid-catalyzed transesterification and Fischer esterification take place by nearly identical mechanisms. Transesterificationcan also take place by a base-catalyzed mechanism, but all attempts at base-catalyzed Fischer esterification (using -OR″,for example) seem doomed to failure. Explain why Fischer esterification cannot be catalyzed by base.2
Acid-catalyzed transesterification and Fischer esterification take place by nearly identical mechanisms. Transesterificationcan also take place by a base-catalyzed mechanism, but all attempts at base-catalyzed Fischer esterification (using -OR″,for example) seem doomed to failure. Explain why Fischer esterification cannot be catalyzed by base.2
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Acid-catalyzed transesterification and Fischer esterification take place by nearly identical mechanisms. Transesterification
can also take place by a base-catalyzed mechanism, but all attempts at base-catalyzed Fischer esterification (using -OR″,
for example) seem doomed to failure. Explain why Fischer esterification cannot be catalyzed by base.
2
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