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Acid anhydrides are often used in place of acid chlorides because a less acidic carboxylic acid, not the much stronger acid HCI, is the byproduct of the reaction. In the following reaction of a carbohydrate derivative, acetic anhydride is used to obtain the product in 99% yield as a single stereoisomer. Note that the stereochemistry of the starting ano- meric carbon is not indicated. Draw the product of the following transformation in a chair form and show the single stereoisomer product of this transformation, which is also the most stable possible chair species. OH anomeric carbon H3C "O-CH3 CH,Cl2 Si

Acid anhydrides are often used in place of acid chlorides because a less acidic carboxylic acid, not the much stronger acid HCI, is the byproduct of the reaction. In the following reaction of a carbohydrate derivative, acetic anhydride is used to obtain the product in 99% yield as a single stereoisomer. Note that the stereochemistry of the starting ano- meric carbon is not indicated. Draw the product of the following transformation in a chair form and show the single stereoisomer product of this transformation, which is also the most stable possible chair species. OH anomeric carbon H3C "O-CH3 CH,Cl2 Si

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Acid anhydrides are often used in place of acid chlorides because a less acidic carboxylic acid, not the much stronger acid HCI, is the byproduct of the reaction. In the following reaction of a carbohydrate derivative, acetic anhydride is used to obtain the product in 99% yield as a single stereoisomer. Note that the stereochemistry of the starting ano- meric carbon is not indicated. Draw the product of the following transformation in a chair form and show the single stereoisomer product of this transformation, which is also the most stable possible chair species. OH anomeric carbon H3C "O-CH3 CH,Cl2 Si
Transcribed Image Text:Acid anhydrides are often used in place of acid chlorides because a less acidic carboxylic acid, not the much stronger acid HCI, is the byproduct of the reaction. In the following reaction of a carbohydrate derivative, acetic anhydride is used to obtain the product in 99% yield as a single stereoisomer. Note that the stereochemistry of the starting ano- meric carbon is not indicated. Draw the product of the following transformation in a chair form and show the single stereoisomer product of this transformation, which is also the most stable possible chair species. OH anomeric carbon H3C "O-CH3 CH,Cl2 Si
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