According to the collision theory of reaction rates, which of the following is/are true? (Select all that apply.) Increasing the concentration of O2 + NO2 would have no effect on the rate of the reaction. In the presence of a catalyst, the value of activation energy for the reaction would be smaller than 211 kJ. Raising the temperature would increase the rate of the reaction by increasing the number of successful O2 + NO2 collisions. Raising the temperature would increase the rate of the reaction because the value of activation energy would be smaller than 211 kJ at a higher temperature. In the presence of a catalyst, the value of energy difference between products and reactant will be smaller than 200 kJ.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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A reaction profile (not to scale!) for the reaction
O2 + NO2
O3 + NO
is shown below:
Increasing energy
O₂ + NO₂
211 kJ
0₂ + NO
200 kJ
Reaction progress
Transcribed Image Text:A reaction profile (not to scale!) for the reaction O2 + NO2 O3 + NO is shown below: Increasing energy O₂ + NO₂ 211 kJ 0₂ + NO 200 kJ Reaction progress
According to the collision theory of reaction rates, which of the following is/are true?
(Select all that apply.)
Increasing the concentration of O₂ + NO2 would have no effect on the rate of the reaction.
In the presence of a catalyst, the value of activation energy for the reaction would be smaller than 211 kJ.
Raising the temperature would increase the rate of the reaction by increasing the number of successful O2 + NO₂ collisions.
Raising the temperature would increase the rate of the reaction because the value of activation energy would be smaller than 211 kJ at a higher
temperature.
In the presence of a catalyst, the value of energy difference between products and reactant will be smaller than 200 kJ.
Transcribed Image Text:According to the collision theory of reaction rates, which of the following is/are true? (Select all that apply.) Increasing the concentration of O₂ + NO2 would have no effect on the rate of the reaction. In the presence of a catalyst, the value of activation energy for the reaction would be smaller than 211 kJ. Raising the temperature would increase the rate of the reaction by increasing the number of successful O2 + NO₂ collisions. Raising the temperature would increase the rate of the reaction because the value of activation energy would be smaller than 211 kJ at a higher temperature. In the presence of a catalyst, the value of energy difference between products and reactant will be smaller than 200 kJ.
Expert Solution
Step 1

Collision theory of reaction rate: According to the collision theory of reaction rate, the randomly moving reactant molecules collide with each other to convert into product molecules.

If the energy of the collision is sufficient enough that it is equal to or greater than the activation energy of the reaction and the reactant molecule collides in the proper orientation, the collision results in the formation of the product. The number of collisions per second between the reactant molecules depends on the concentraion of reactants and temperature of the reaction.

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