Absorbance Questions 2-4 refer to the absorption spectrum for a 0.80M solution of metal M and a calibration curve for the metal M2 collected in a 1.5 cm cuvette, shown in Figures 2 and 3. 60 0.7 0.5 9'0 vo 0.3 zo zo 00 Wavelength (nm) 00 1.2 009 000 R0 9'0 [M2+] (M) Figure 2. Absorption spectrum of 0.80 M M2+ Figure 3. Calibration curve for M2 2. At what wavelength was the calibration curve obtained? Use the data from both graphs to explain your choice. 3. Would the value of the molar absorptivity (E) be greater, lesser or equal for M2 for the absorbance of light at 400. nm vs. 650. nm. Use the data from Figure 2 to explain your choice. Using the calibration curve in Figure 3: A sample of a solution of unknown concentration of M2* has an absorbance reading that is "off scale" because the absorbance was measured to be above 0.8. You dilute this sample by adding 5.0 mL of water to 1.0 mL of the solution of M2 The absorbance of the diluted solution was determined to be 0.35 at the same wavelength used for the calibration curve. What is the concentration of M2, in M, of the original undiluted sample?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Please answer question number 4 and show all work explaining how you got the answer. thank you 

Absorbance
Questions 2-4 refer to the absorption spectrum for a 0.80M solution of metal M
and a
calibration curve for the metal M2 collected in a 1.5 cm cuvette, shown in Figures 2
and 3.
60
0.7
0.5
9'0
vo
0.3
zo
zo
00
Wavelength (nm)
00
1.2
009
000
R0
9'0
[M2+] (M)
Figure 2. Absorption spectrum of 0.80 M M2+
Figure 3. Calibration curve for M2
2. At what wavelength was the calibration curve obtained? Use the data from both
graphs to explain your choice.
3. Would the value of the molar absorptivity (E) be greater, lesser or equal for M2 for the
absorbance of light at 400. nm vs. 650. nm. Use the data from Figure 2 to explain
your choice.
Using the calibration curve in Figure 3: A sample of a solution of unknown
concentration of M2* has an absorbance reading that is "off scale" because the
absorbance was measured to be above 0.8. You dilute this sample by adding 5.0 mL
of water to 1.0 mL of the solution of M2 The absorbance of the diluted solution was
determined to be 0.35 at the same wavelength used for the calibration curve. What is
the concentration of M2, in M, of the original undiluted sample?
Transcribed Image Text:Absorbance Questions 2-4 refer to the absorption spectrum for a 0.80M solution of metal M and a calibration curve for the metal M2 collected in a 1.5 cm cuvette, shown in Figures 2 and 3. 60 0.7 0.5 9'0 vo 0.3 zo zo 00 Wavelength (nm) 00 1.2 009 000 R0 9'0 [M2+] (M) Figure 2. Absorption spectrum of 0.80 M M2+ Figure 3. Calibration curve for M2 2. At what wavelength was the calibration curve obtained? Use the data from both graphs to explain your choice. 3. Would the value of the molar absorptivity (E) be greater, lesser or equal for M2 for the absorbance of light at 400. nm vs. 650. nm. Use the data from Figure 2 to explain your choice. Using the calibration curve in Figure 3: A sample of a solution of unknown concentration of M2* has an absorbance reading that is "off scale" because the absorbance was measured to be above 0.8. You dilute this sample by adding 5.0 mL of water to 1.0 mL of the solution of M2 The absorbance of the diluted solution was determined to be 0.35 at the same wavelength used for the calibration curve. What is the concentration of M2, in M, of the original undiluted sample?
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Knowledge Booster
Green Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY