Absorbance (b) -490 nm x=20 300 CIT 400 500 670 λ/nm 25 20 15 / 10 cm-¹ Figure 1 UV-vis absorption spectrum of [Ti(OH2)6]³+. (a) Figure 1 shows the UV-vis absorption spectrum of [Ti(OH₂)6]³+. The band shown in the figure is not symmetric and suggests that more than one state is involved. Explain this observation using the Jahn-Teller effect. Chromium is a member of group 6 of the transition metals. Chromium complexes most commonly exist in +3 and +6 oxidation states. Discuss why the solutions of [Cr(H₂O)6]³+ and [CrO4]2- have a pale green and intense yellow, respectively. 16 markol

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Kindly answer question a, b

Absorbance
(b)
A-490 nm
20 300 cm
II
1
400
500
670
λ/nm
25
20
15
/10³cm-1
Figure 1 UV-vis absorption spectrum of [Ti(OH₂)6]³+.
(a)
Figure 1 shows the UV-vis absorption spectrum of [Ti(OH2)6]³+. The band
shown in the figure is not symmetric and suggests that more than one
state is involved. Explain this observation using the Jahn-Teller effect.
Chromium is a member of group 6 of the transition metals. Chromium
complexes most commonly exist in +3 and +6 oxidation states. Discuss
why the solutions of [Cr(H₂O)6]³+ and [CrO4]²- have a pale green and
intense yellow, respectively.
16 markol
Transcribed Image Text:Absorbance (b) A-490 nm 20 300 cm II 1 400 500 670 λ/nm 25 20 15 /10³cm-1 Figure 1 UV-vis absorption spectrum of [Ti(OH₂)6]³+. (a) Figure 1 shows the UV-vis absorption spectrum of [Ti(OH2)6]³+. The band shown in the figure is not symmetric and suggests that more than one state is involved. Explain this observation using the Jahn-Teller effect. Chromium is a member of group 6 of the transition metals. Chromium complexes most commonly exist in +3 and +6 oxidation states. Discuss why the solutions of [Cr(H₂O)6]³+ and [CrO4]²- have a pale green and intense yellow, respectively. 16 markol
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