A4.830-g sample containing KCl and KCIO, was dissolved in sufficient water to give 250.00 ml of solution. A 50.00-ml portion of the solution required 42.29 ml. of 0.0750 M AgNO, in a Mohr titration. Next. a 25.00-ml portion of the original solution was treated with V₂(SO4)3 to reduce the perchlorate lon to chloride. 8 V³+ (aq) + CIO, (aq) +12 H₂O() - Cl(aq) +8 VO³+ (aq) +8 H₂O* (aq) and the resulting solution was titrated with AgNO,. This titration required 38.08 mL of 0.0750 M AgNO, What is the mass percent of KCI and KCIO4 in the mixture? KCI KCIO

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A4.830-g sample containing KCl and KCIO, was dissolved in sufficient water to give 250.00 ml of solution. A 50.00-ml portion of the solution required 42.29 ml of
0.0750 M AgNO, in a Mohr titration. Next. a 25.00-ml portion of the original solution was treated with V₂(SO4)3 to reduce the perchlorate ion to chloride.
8 V³+ (aq) + CIO, (aq) +12 H₂O() → Cl(aq) +8 VO³+ (aq) +8 H₂O* (aq)
and the resulting solution was titrated with AgNO,. This titration required 38.08 mL of 0.0750 M AgNO, What is the mass percent of KCI and KCIO4 in the
mixture?
KCI
KCIO
Transcribed Image Text:A4.830-g sample containing KCl and KCIO, was dissolved in sufficient water to give 250.00 ml of solution. A 50.00-ml portion of the solution required 42.29 ml of 0.0750 M AgNO, in a Mohr titration. Next. a 25.00-ml portion of the original solution was treated with V₂(SO4)3 to reduce the perchlorate ion to chloride. 8 V³+ (aq) + CIO, (aq) +12 H₂O() → Cl(aq) +8 VO³+ (aq) +8 H₂O* (aq) and the resulting solution was titrated with AgNO,. This titration required 38.08 mL of 0.0750 M AgNO, What is the mass percent of KCI and KCIO4 in the mixture? KCI KCIO
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