a. State the van-der-Waals equation for real gases and explain the variables.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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a. State the van-der-Waals equation for real gases and explain the variables.
b. Diethyl sulphide has a critical temperature of 285 °C and a critical density of
0.284 kg L-1. Calculate the van-der-Waals coefficients a and b.
c. Using those coefficients, calculate the pressure present when 52 moles of diethyl
sulphide are stored in a 15 L container at 100 °C?
d. Given that the storage container is quite brittle, it may only withstand 25 bar.
Calculate at which temperature the container would burst. Use both the ideal gas
and the van-der-Waals equation.
Transcribed Image Text:a. State the van-der-Waals equation for real gases and explain the variables. b. Diethyl sulphide has a critical temperature of 285 °C and a critical density of 0.284 kg L-1. Calculate the van-der-Waals coefficients a and b. c. Using those coefficients, calculate the pressure present when 52 moles of diethyl sulphide are stored in a 15 L container at 100 °C? d. Given that the storage container is quite brittle, it may only withstand 25 bar. Calculate at which temperature the container would burst. Use both the ideal gas and the van-der-Waals equation.
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