a. Consider a speed of 1800 m/s; at which temperature (300 or 1000 K) is the fraction of N2 molecules per unit speed interval the greatest? b. b. Consider a speed of 50 m/s; at which temperature (300 or 1000 K) is the fraction of N2 molecules per unit speed interval the greatest?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

a. Consider a speed of 1800 m/s; at which temperature (300 or 1000 K) is the fraction of N2 molecules per unit speed interval the greatest? b.

b. Consider a speed of 50 m/s; at which temperature (300 or 1000 K) is the fraction of N2 molecules per unit speed interval the greatest?

8
ChemActivity G1 Gases (I)
Model 5: The Maxwell Distribution of Molecular Speeds.
Not all gas particles within a collection of particles (at constant temperature) have
the same velocity-some particles are moving slowly, others are moving rapidly. The
problem of how to determine the most probable distribution of speeds was solved by J.
Clerk Maxwell. Starting with the following assumptions,
The probability of a molecular state depends only on the energy of the molecular
state.
The same probability distribution applies for all kinds of molecules.
Maxwell's equation for the distribution of speeds is the following:
4nv2( m3/2 e-mv2/2kT
2TKT
fraction of molecules per unit speed interval =
(7)
where k (Boltzmann's constant) = 1.38066 x 10-23 JK-4
%3D
Table 1. The Speeds of Gaseous N2 Molecules.
fraction of molecules
fraction of molecules
molecule per unit speed interval per unit speed interval
at 300 K
(s/m)
speed of
(m/s)
at 1000 K
(s/m)
0.
25
1.87 x 10-5
7.40 x 10-5
2.84 x 10-4
9.60 x 10-4
1.63 x 10-3
1.96 x 10-3
1.84 x 10-3
1.43 x 10-3
9.39 x 10-4
5.28 x 10-4
1.09 x 10-4
4.07 x 10-5
1.33 x 10-5
3.84 x 10-6
9.77 x 10-7
2.20 x 10-7
4.39 x 10-8
7.77 x 10-9
1.22 x 10-9
1.70 x 10-10
2.11 x 10-11
3.08 x 10-6
1.23 x 10-5
4.85 x 10-5
1.85 x 10-4
3.82 x 10-4
6.03 x 10-4
8.10 x 10-4
9.69 x 10-4
1.06 x 10-3
1.07 x 10-3
9.15 x 10-4
7.78 x 10-4
6.28 x 10-4
4.84 x 10-4
3.56 x 10-4
2.51 x 10-4
1.69 x 10-4
1.10 x 10-4
6.81 x 10-5
4.07 x 10-5
2.34 x 10-5
50
100
200
300
400
500
600
700
800
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
Transcribed Image Text:8 ChemActivity G1 Gases (I) Model 5: The Maxwell Distribution of Molecular Speeds. Not all gas particles within a collection of particles (at constant temperature) have the same velocity-some particles are moving slowly, others are moving rapidly. The problem of how to determine the most probable distribution of speeds was solved by J. Clerk Maxwell. Starting with the following assumptions, The probability of a molecular state depends only on the energy of the molecular state. The same probability distribution applies for all kinds of molecules. Maxwell's equation for the distribution of speeds is the following: 4nv2( m3/2 e-mv2/2kT 2TKT fraction of molecules per unit speed interval = (7) where k (Boltzmann's constant) = 1.38066 x 10-23 JK-4 %3D Table 1. The Speeds of Gaseous N2 Molecules. fraction of molecules fraction of molecules molecule per unit speed interval per unit speed interval at 300 K (s/m) speed of (m/s) at 1000 K (s/m) 0. 25 1.87 x 10-5 7.40 x 10-5 2.84 x 10-4 9.60 x 10-4 1.63 x 10-3 1.96 x 10-3 1.84 x 10-3 1.43 x 10-3 9.39 x 10-4 5.28 x 10-4 1.09 x 10-4 4.07 x 10-5 1.33 x 10-5 3.84 x 10-6 9.77 x 10-7 2.20 x 10-7 4.39 x 10-8 7.77 x 10-9 1.22 x 10-9 1.70 x 10-10 2.11 x 10-11 3.08 x 10-6 1.23 x 10-5 4.85 x 10-5 1.85 x 10-4 3.82 x 10-4 6.03 x 10-4 8.10 x 10-4 9.69 x 10-4 1.06 x 10-3 1.07 x 10-3 9.15 x 10-4 7.78 x 10-4 6.28 x 10-4 4.84 x 10-4 3.56 x 10-4 2.51 x 10-4 1.69 x 10-4 1.10 x 10-4 6.81 x 10-5 4.07 x 10-5 2.34 x 10-5 50 100 200 300 400 500 600 700 800 1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000
Expert Solution
steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Mole Concept
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY