a. Calculate the pH of a 0.2 M acetate buffer (a solution containing 0.1 mol L-l acetic acid and 0.1 mol L- sodium acetate), given that the pKa of acetic acid is 4.7. b. What would be the pH value after adding 0.05 mol of NaOH to 1 L of 0.2 mol L' acetate buffer? c. Compare the pH value in (b) with that obtained after adding 0.05 mol NaOH to 1 L of water (a simple solution of 0.05 mol L·1 NaOH).

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7. Refer to the following table:
Table 2-2. Change in pH of 0.2 M Acetate Buffer after addition of Acid or Base
[Base]:[Acid]
0.005:0.195
Addition
pH
HC1 0.095 mol
3.1
HC1 0.075
0.025:0.175
3.9
HС1 0.05
НС1 0.025
0.05:0.15
4.2
0.075:0.125
4.5
0.1:0.1
0.125:0.075
4.7
NaOH 0.025 mol
4.9
NaOH 0.05 mol
0.15:0.05
5.2
NaOH 0.75 mol
0.175:0.025
5.5
NaOH 0.095 mol
0.195:0.005
6.3
a. Calculate the pH of a 0.2 M acetate buffer (a solution containing 0.1 mol L-' acetic acid and 0.1 mol L-1
sodium acetate), given that the pKa of acetic acid is 4.7.
b. What would be the pH value after adding 0.05 mol of NaOH to 1 L of 0.2 mol L1 acetate buffer?
c. Compare the pH value in (b) with that obtained after adding 0.05 mol NAOH to 1 L of water (a simple
solution of 0.05 mol L-' NaOH).
d. How much acid or base can be added to 1 L of the 0.2 M acetate buffer so that the pH does not change
appreciably (i.e., what is its buffer range)?
Transcribed Image Text:7. Refer to the following table: Table 2-2. Change in pH of 0.2 M Acetate Buffer after addition of Acid or Base [Base]:[Acid] 0.005:0.195 Addition pH HC1 0.095 mol 3.1 HC1 0.075 0.025:0.175 3.9 HС1 0.05 НС1 0.025 0.05:0.15 4.2 0.075:0.125 4.5 0.1:0.1 0.125:0.075 4.7 NaOH 0.025 mol 4.9 NaOH 0.05 mol 0.15:0.05 5.2 NaOH 0.75 mol 0.175:0.025 5.5 NaOH 0.095 mol 0.195:0.005 6.3 a. Calculate the pH of a 0.2 M acetate buffer (a solution containing 0.1 mol L-' acetic acid and 0.1 mol L-1 sodium acetate), given that the pKa of acetic acid is 4.7. b. What would be the pH value after adding 0.05 mol of NaOH to 1 L of 0.2 mol L1 acetate buffer? c. Compare the pH value in (b) with that obtained after adding 0.05 mol NAOH to 1 L of water (a simple solution of 0.05 mol L-' NaOH). d. How much acid or base can be added to 1 L of the 0.2 M acetate buffer so that the pH does not change appreciably (i.e., what is its buffer range)?
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