а. 1) LIAIH4 pyridine Ph3CCPh Ph3CH PHCH2OH + 2) H-О, H*

Chemistry
10th Edition
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Suggest mechanisms for the following:

а.
1) LIAIH4
pyridine
Ph3CCPh
Ph3CH
PHCH2OH
+
2) H20, H*
b.
H. H
HO
Ph
||
PHCCH2OH +
pyridine
PHCHCH=0
heat
Ph
Н ОН
OH
c. Treatment of the cis and trans isomers of 1,2-dimethyl-2-phenylcyclopentanol
with 0.25 M NaCH,SOCH, in DMSO leads to an 72:28 equilibrium mixture
favoring the trans isomer.
ОН
CH3 ,
ОН
CH3 ,
Ph
Ph
"CH3
CH3
cis
trans
Transcribed Image Text:а. 1) LIAIH4 pyridine Ph3CCPh Ph3CH PHCH2OH + 2) H20, H* b. H. H HO Ph || PHCCH2OH + pyridine PHCHCH=0 heat Ph Н ОН OH c. Treatment of the cis and trans isomers of 1,2-dimethyl-2-phenylcyclopentanol with 0.25 M NaCH,SOCH, in DMSO leads to an 72:28 equilibrium mixture favoring the trans isomer. ОН CH3 , ОН CH3 , Ph Ph "CH3 CH3 cis trans
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