(a) What is the theoretical melting point for a mixture containing 80% by mole of A? (b) Describe the change in composition of the solution containing a mole fraction of 0.10 A as the temperature increases from 132 to 133°C? 138 136 134 132 130 0.00 0.20 0.40 0.60 0.80 1.00 ХА 4. Why must the spot be applied to the TLC plate above the level of development solvent? 5. A Grignard reaction of phenylmagnesium bromide with 3-pentanone gives 3-phenylpentan- 3-ol as the major product (we will discuss this reaction later). The crude product contains the 3-phenylpentan-3-ol product, unreacted 3-pentanone, and biphenyl (a side product). A developing solvent is found that separates the mixture into three spots on a silica gel TLC plate. Considering the functional groups present, predict which compounds would have the smallest and largest Rf values. Briefly justify your answer. Temperature (°C)

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3. Use the eutectic diagram on the following page for the following questions.

(a) What is the theoretical melting point for a mixture containing 80% by mole of A?

(b) Describe the change in composition of the solution containing a mole fraction of 0.10 A as the temperature increases from 132 to 133°C?

**Diagram Explanation:**
- The diagram is a phase diagram showing the relationship between temperature (in °C) and mole fraction (Xₐ) of component A.
- The temperature ranges from 130°C to 138°C.
- The mole fraction (Xₐ) ranges from 0.00 to 1.00.
- The graph shows a curve with a minimum point, indicating the eutectic point.

4. Why must the spot be applied to the TLC plate above the level of development solvent?

5. A Grignard reaction of phenylmagnesium bromide with 3-pentanone gives 3-phenylpentan-3-ol as the major product (we will discuss this reaction later). The crude product contains the 3-phenylpentan-3-ol product, unreacted 3-pentanone, and biphenyl (a side product). A developing solvent is found that separates the mixture into three spots on a silica gel TLC plate. Considering the functional groups present, predict which compounds would have the smallest and largest Rf values. Briefly justify your answer.
Transcribed Image Text:3. Use the eutectic diagram on the following page for the following questions. (a) What is the theoretical melting point for a mixture containing 80% by mole of A? (b) Describe the change in composition of the solution containing a mole fraction of 0.10 A as the temperature increases from 132 to 133°C? **Diagram Explanation:** - The diagram is a phase diagram showing the relationship between temperature (in °C) and mole fraction (Xₐ) of component A. - The temperature ranges from 130°C to 138°C. - The mole fraction (Xₐ) ranges from 0.00 to 1.00. - The graph shows a curve with a minimum point, indicating the eutectic point. 4. Why must the spot be applied to the TLC plate above the level of development solvent? 5. A Grignard reaction of phenylmagnesium bromide with 3-pentanone gives 3-phenylpentan-3-ol as the major product (we will discuss this reaction later). The crude product contains the 3-phenylpentan-3-ol product, unreacted 3-pentanone, and biphenyl (a side product). A developing solvent is found that separates the mixture into three spots on a silica gel TLC plate. Considering the functional groups present, predict which compounds would have the smallest and largest Rf values. Briefly justify your answer.
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