(a) What is the molar absorptivity of compound Z at 295 nm and 348nm, given the absorption spectrum shown in Fig.22-14 (which was obtained using a UV-Vis spectrophotometer and a 1mM solution of compound Z in a sample cell with a path length of 1 cm)? (b) Now you have decided to make quantitative measurement of the level of compound Z in different solutions. Based on the above spectrum, which wavelength will you use for your measurements? Give two reasons why this is the optimum wavelength.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter13: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 13.28P
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  1. (a) What is the molar absorptivity of compound Z at 295 nm and 348nm, given the absorption spectrum shown in Fig.22-14 (which was obtained using a UV-Vis spectrophotometer and a 1mM solution of compound Z in a sample cell with a path length of 1 cm)?

(b) Now you have decided to make quantitative measurement of the level of compound Z in different solutions. Based on the above spectrum, which wavelength will you use for your measurements? Give two reasons why this is the optimum wavelength.

1.0
.9
.8-
.7-
.3
.2
.1-
280
300
320
340
360
380
400
Wavelength (nm)
22-14
figure
Absorption spectrum of compound Z, to be
used in conjunction with problems 4(a) and
4(b).
Absorbance (A)
4.
Transcribed Image Text:1.0 .9 .8- .7- .3 .2 .1- 280 300 320 340 360 380 400 Wavelength (nm) 22-14 figure Absorption spectrum of compound Z, to be used in conjunction with problems 4(a) and 4(b). Absorbance (A) 4.
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