(a) What is the molar absorptivity of compound Z at 295 nm and 348nm, given the absorption spectrum shown in Fig.22-14 (which was obtained using a UV-Vis spectrophotometer and a 1mM solution of compound Z in a sample cell with a path length of 1 cm)? (b) Now you have decided to make quantitative measurement of the level of compound Z in different solutions. Based on the above spectrum, which wavelength will you use for your measurements? Give two reasons why this is the optimum wavelength.
(a) What is the molar absorptivity of compound Z at 295 nm and 348nm, given the absorption spectrum shown in Fig.22-14 (which was obtained using a UV-Vis spectrophotometer and a 1mM solution of compound Z in a sample cell with a path length of 1 cm)? (b) Now you have decided to make quantitative measurement of the level of compound Z in different solutions. Based on the above spectrum, which wavelength will you use for your measurements? Give two reasons why this is the optimum wavelength.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter13: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 13.28P
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Question
- (a) What is the molar absorptivity of compound Z at 295 nm and 348nm, given the absorption spectrum shown in Fig.22-14 (which was obtained using a UV-Vis spectrophotometer and a 1mM solution of compound Z in a sample cell with a path length of 1 cm)?
(b) Now you have decided to make quantitative measurement of the level of compound Z in different solutions. Based on the above spectrum, which wavelength will you use for your measurements? Give two reasons why this is the optimum wavelength.
![1.0
.9
.8-
.7-
.3
.2
.1-
280
300
320
340
360
380
400
Wavelength (nm)
22-14
figure
Absorption spectrum of compound Z, to be
used in conjunction with problems 4(a) and
4(b).
Absorbance (A)
4.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5f0d24f1-00ea-43dc-9fd1-435dc741eb9f%2F11dc9770-e9da-4e3d-9488-00180e0cbf77%2Ftqevrjs_processed.png&w=3840&q=75)
Transcribed Image Text:1.0
.9
.8-
.7-
.3
.2
.1-
280
300
320
340
360
380
400
Wavelength (nm)
22-14
figure
Absorption spectrum of compound Z, to be
used in conjunction with problems 4(a) and
4(b).
Absorbance (A)
4.
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