A voltaic cell is set up such that one half-cell is W3+|W (E = 0.1 V) and the other is Zr4+|Zr (E = −1.45 V). The tungsten half-cell is under standard conditions. Enough sodium phosphate is added to the zirconium half-cell to precipitate most of the zirconium ion and make the equilibrium concentration of phosphate 0.0347 M. The cell potential under these conditions at 25.0 ∘C is 1.58 V. What is the solubility product constant of zirconium(IV) phosphate?
A voltaic cell is set up such that one half-cell is W3+|W (E = 0.1 V) and the other is Zr4+|Zr (E = −1.45 V). The tungsten half-cell is under standard conditions. Enough sodium phosphate is added to the zirconium half-cell to precipitate most of the zirconium ion and make the equilibrium concentration of phosphate 0.0347 M. The cell potential under these conditions at 25.0 ∘C is 1.58 V. What is the solubility product constant of zirconium(IV) phosphate?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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A voltaic cell is set up such that one half-cell is W3+|W (E = 0.1 V) and the other is Zr4+|Zr (E = −1.45 V). The tungsten half-cell is under standard conditions. Enough sodium phosphate is added to the zirconium half-cell to precipitate most of the zirconium ion and make the equilibrium concentration of phosphate 0.0347 M. The cell potential under these conditions at 25.0 ∘C is 1.58 V. What is the solubility product constant of zirconium(IV) phosphate?
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