A typical coal-fired electric generating plant will burn about 3 metric tons of coal per hour. Most of the coal burned in the United States contains 1 to 4 % by weight sulfur in the form of pyrite, which is oxidized as the coal burns: 4FeS2(s) + 11 O₂(g) 2 Fe2O3(s) + 8 SO2(9) Once in the atmosphere, the SO₂ is oxidized to SO3, which then reacts with water in the atmosphere to form sulfuric acid: SO3(9) + H₂O(1)→ H₂SO4 (aq) If 42.4 metric tons of coal that contains 1.44 % by weight S is burned and all of the sulfuric acid that is formed rains down into a pond of dimensions 397 m x 256 m x 4.96 m, what is the pH of the pond? (OK to assume 2 mol H30+ per mole H₂SO4.) Hint: 1 metric ton = 1000 kg

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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A typical coal-fired electric generating plant will burn about 3 metric tons of coal
per hour.
Most of the coal burned in the United States contains 1 to 4 % by weight sulfur
in the form of pyrite, which is oxidized as the coal burns:
4FeS2(s) + 11 O₂(g) 2 Fe2O3(s) + 8 SO2(9)
Once in the atmosphere, the SO2 is oxidized to SO3, which then reacts with
water in the atmosphere to form sulfuric acid:
SO3(9) + H₂O(1)→→→→→→→ H₂SO4(aq)
If 42.4 metric tons of coal that contains 1.44 % by weight S is burned and all
of the sulfuric acid that is formed rains down into a pond of dimensions 397 m x
256 m x 4.96 m, what is the pH of the pond? (OK to assume 2 mol H30+ per
mole H₂SO4.)
Hint: 1 metric ton = 1000 kg
Transcribed Image Text:A typical coal-fired electric generating plant will burn about 3 metric tons of coal per hour. Most of the coal burned in the United States contains 1 to 4 % by weight sulfur in the form of pyrite, which is oxidized as the coal burns: 4FeS2(s) + 11 O₂(g) 2 Fe2O3(s) + 8 SO2(9) Once in the atmosphere, the SO2 is oxidized to SO3, which then reacts with water in the atmosphere to form sulfuric acid: SO3(9) + H₂O(1)→→→→→→→ H₂SO4(aq) If 42.4 metric tons of coal that contains 1.44 % by weight S is burned and all of the sulfuric acid that is formed rains down into a pond of dimensions 397 m x 256 m x 4.96 m, what is the pH of the pond? (OK to assume 2 mol H30+ per mole H₂SO4.) Hint: 1 metric ton = 1000 kg
An aqueous solution of trichloroacetic acid, that is 1.00 percent by weight
trichloroacetic acid, has a density of 1.0034 g/mL. A student determines that
the freezing point of this solution is -0.220 °C.
Based on the observed freezing point, what is the percent ionization of the acid
and the value of Ka?
Ky for H₂O is 1.86 °C/m.
% ionized-
Ka
%
Transcribed Image Text:An aqueous solution of trichloroacetic acid, that is 1.00 percent by weight trichloroacetic acid, has a density of 1.0034 g/mL. A student determines that the freezing point of this solution is -0.220 °C. Based on the observed freezing point, what is the percent ionization of the acid and the value of Ka? Ky for H₂O is 1.86 °C/m. % ionized- Ka %
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