A titration of 35.0 mL of an unknown tribasic salt, Li₃A, requires 90.00 mL of 0.250 M HCl to reach the 3rd equivalence point. The titration data is shown below: Vol of HCl (mL) 15.00 30.00 45.00 60.00 75.00 90.00 pH 10.45 8.62 6.79 4.86 2.93 1.35 What is the value of Kb₁ of A³⁻?

Chemistry: Principles and Practice
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter16: Reactions Between Acids And Bases
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Problem 16.54QE
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A titration of 35.0 mL of an unknown tribasic salt, Li₃A, requires 90.00 mL of 0.250 M HCl to reach the 3rd equivalence point. The titration data is shown below:

Vol of HCl (mL) 15.00 30.00 45.00 60.00 75.00 90.00

pH 10.45 8.62 6.79 4.86 2.93 1.35

What is the value of Kb₁ of A³⁻?

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