A student proposed the following mechanism for the gas phase reaction of fluorine with chlorine dioxide. step 1 fast: 2 Cl0,=Cl,0, step 2 slow: Cl,04+F2→2 FC102 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Enter the formula of any species that acts as a reaction intermediate? If none leave box blank: (3) Complete the rate law for the overall reaction that is consistent with this mechanism. Use the form k[A]™[B]"... , where '1' is understood (so don't write it if it's a 'l') for m, n etc. Rate =

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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A student proposed the following mechanism for the gas phase reaction of fluorine with chlorine dioxide.
step 1 fast:
2 C10,=Cl,04
step 2
slow: Ch04 + F2 →2 FC10,
(1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank.
(2) Enter the formula of any species that acts as a reaction intermediate? If none leave box blank:
(3) Complete the rate law for the overall reaction that is consistent with this mechanism.
Use the form k[A]"[B]"... , where '1' is understood (so don't write it if it's a '1') for m, n etc.
Rate =
Transcribed Image Text:A student proposed the following mechanism for the gas phase reaction of fluorine with chlorine dioxide. step 1 fast: 2 C10,=Cl,04 step 2 slow: Ch04 + F2 →2 FC10, (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Enter the formula of any species that acts as a reaction intermediate? If none leave box blank: (3) Complete the rate law for the overall reaction that is consistent with this mechanism. Use the form k[A]"[B]"... , where '1' is understood (so don't write it if it's a '1') for m, n etc. Rate =
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