A student mistakenly added conce

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4. A student mistakenly added concentrated (12M)
HCI to a sample of unknown, instead of adding 6M
HCI, as directed.
(1) At first, a large amount of light-colored pre-
cipitate formed, but some dissolved on further addi-
tion of concentrated HCI. Write an equation(s) for the
reaction(s) that might have occurred.
(2) The precipitate was separated from the
supernatant liquid in (1) and was found to be insoluble
in hot water. The precipitate turned grey-black upon
addition of 6M NH2. The student concluded that the
unknown contained Hg,2+ ion. The student received
ona low mark on the experiment, because the unknown
actually contained all three Group I cations. Explain
what happened.
Transcribed Image Text:4. A student mistakenly added concentrated (12M) HCI to a sample of unknown, instead of adding 6M HCI, as directed. (1) At first, a large amount of light-colored pre- cipitate formed, but some dissolved on further addi- tion of concentrated HCI. Write an equation(s) for the reaction(s) that might have occurred. (2) The precipitate was separated from the supernatant liquid in (1) and was found to be insoluble in hot water. The precipitate turned grey-black upon addition of 6M NH2. The student concluded that the unknown contained Hg,2+ ion. The student received ona low mark on the experiment, because the unknown actually contained all three Group I cations. Explain what happened.
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