A still is charged with 1000 moles of a binary mixture that is 87.3 mole % of light (more volatile) Methanol and remainder heavier (less volatile) component isopropyl alcohol. This mixture is distilled until 50 moles remain in the still and the cumulative distillate is collected. You may assume that the relative volatility (Light-Heavy = 2.054) remains constant during the distillation process and equilibrium data and an initial analysis of the Rayleigh equation is provided in the table provided. methanol isopropyl alcohol Temp Pvp (mmHg) Pvp (mmHg) (°C) 764.2 360 3 500 Volatile Component X Y Integral 1/(y-x) Ax"Avg(1/(-x)) Summation
A still is charged with 1000 moles of a binary mixture that is 87.3 mole % of light (more volatile) Methanol and remainder heavier (less volatile) component isopropyl alcohol. This mixture is distilled until 50 moles remain in the still and the cumulative distillate is collected. You may assume that the relative volatility (Light-Heavy = 2.054) remains constant during the distillation process and equilibrium data and an initial analysis of the Rayleigh equation is provided in the table provided. methanol isopropyl alcohol Temp Pvp (mmHg) Pvp (mmHg) (°C) 764.2 360 3 500 Volatile Component X Y Integral 1/(y-x) Ax"Avg(1/(-x)) Summation
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
100%
Batch Distillation

Transcribed Image Text:A still is charged with 1000 moles of a binary mixture that is 87.3 mole% of light (more volatile) Methanol and remainder heavier (less volatile) component isopropyl
alcohol.
This mixture is distilled until 50 moles remain in the still and the cumulative distillate is collected.
You may assume that the relative volatility (Light-Heavy = 2.054) remains constant during the distillation process and equilibrium data and an initial analysis of the
Rayleigh equation is provided in the table provided.
methanol
764.2
782.0
800.2
818.7
837.5
856.8
isopropyl
alcohol
Pvp (mmHg) Pvp (mmHg) (°C)
64.65
65.24
65.82
66.41
876.4
896.3
916.7
9374
958.5
980.0
1001.9
1024.2
1046 9
1070.1
1093.6
11176
11420
1166.9
1192 2
1217.9
1244.1
1270.8
1297.9
1325.6
1353.7
1382.2
1411.3
1440.9
1471.0
1471.0
360.3
370.0
379.8
389.9
400.2
410.7
421.4
432.4
443.6
455.1
466.8
478.8
491 0
503.5
516.3
529 3
542.6
556.2
570.0
584.2
598.6
613.4
628.4
643 S
559.4
675.4
691.7
Temp
708.4
725.3
742.6
760.3
760.3
67.00
67.58
68.17
68.76
69.34
69.93
70.52
71.10
71.69
72.28
72.86
73.45
74 04
74.62
75.21
75.80
76.38
76.97
77.56
78.14
78.73
79.32
79.90
$0.49
$1.08
81.66
82.25
32.25
Volatile Component
Y
1.000 1.000
0.957 0.979
0.914
0.957
0.873
0.832
0.792
0.753
0.864
0.715
0.839
0.678
0.813
0.641
0.786
0.605 0.759
0.569
0.730
0 535
0.701
0.501
0.671
0467
0.640
0.434 0.608
0.402
0.575
0.542
0.507
0.472
0.435
0.398
0.220
0.359
0.192
0.319
0.164
0.279
0.137 0.237
0.109 0.194
0.083
0.150
0.057
0.105
0.031
0.058
0.006
0.011
0.000
0.000
0.370
0339
0 309
0 279
0.249
0.935
0.912
0.888
1/(y-x) Ax*Avg(1/(y-x))
16.063
12.515
10.414
9.041
8.086
7.395
6.884
6.502
6.218
6.012
5.870
5.785
5.752
5.768
5.836
5.959
6.143
6.402
6.752
7.221
7.855
8.728
9.971
11.843
14.926
20.846
36.378
196.417
0.581
0.457
0.380
0.328
0.290
0.263
0.241
0.225
0.212
0.202
0.195
0.189
0.186
0.184
0.183
0.185
0.188
0.194
0 202
0215
0232
0.257
0.295
0.356
0.468
0.740
2.955
Integral
Summation
0.581
1.037
1.417
1.745
2.035
2.298
2.539
2.764
2.977
3.179
3.374
3.563
3.749
3.932
4.116
4.300
4.488
4.682
4.884
5.099
5.331
5.588
5.883
6.240
6.708
7.448
10 403
Using the data provided
a) What is the composition of the very first bubble vaporized in this process? Mole fraction of light component YA = 0.935
Molo fraction of light component vA -

Transcribed Image Text:Isopropyl
alcohol
Pvp (mmHg) Pvp (mmHg)
methanol
782.0
800.2
818.7
837.5
876.4
980.0
1001.9
1046.9
1325 6
1440.9
421.4
443.6
466.8
491 0
5163
570.0
598 6
675 4
691.T
708.4
725 3
Temp
66.41
67.00
68.17
69.34
74 04
75.50
76.33
76.97
77.56
78.73
79.32
79.90
30.49
31.66
Volatile Component
X
0.914
0.832
0,715
0.541
0.605
0.569
0 535
0.402
0339
0.309
0.279
0.192
0.164
0.467 0.640
0.608
0.109
0.083
0.057
V
0.006
0.000
0.979
0.364
0.786
0.507
0.472
0.435
1/[y-x) Ax*Avg(1/([y-x))
16.063
12 515
8.086
6.012
5.785
5.836
6.143
7.855
8.728
9.971
11.843
14.926
36.578
196 417
0.380
0.290
0 189
0.186
0.184
0.185
0 188
0215
0 356
0163
Integral
Summation
0 581
2.298
4 116
4.300
4.884
4.883
6.240
6.708
Using the data provided
a) What is the composition of the very first bubble vaporized in this process? Mole fraction of light component YA = 0.935
b) What is the composition of the last bubble vaporized in the process? Mole fraction of light component YA =
c) What is the composition of the residue remaining in the still, Mole fraction of light component XA =
d) What is the average mole fraction of the distillate? Yavg=
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