A solution of sodium thiosulfate, Na2S2O3 was standardized by dissolving 0.188 g of KIO3 (MM = 214.00) in water, adding a large excess of KI, and acidifying with HCl.  The liberated iodine required 18.25 mL of the thiosulfate solution to decolorize the blue starch/iodine complex. Calculate the molarity of Na2S2O3 solution. Stoichiometry of the reaction is: 1 mol IO3-  = 3 mol I2 = 6 mol S2O32

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A solution of sodium thiosulfate, Na2S2O3 was standardized by dissolving 0.188 g of KIO3 (MM = 214.00) in water, adding a large excess of KI, and acidifying with HCl.  The liberated iodine required 18.25 mL of the thiosulfate solution to decolorize the blue starch/iodine complex. Calculate the molarity of Na2S2O3 solution.

Stoichiometry of the reaction is:

1 mol IO3-  = 3 mol I2 = 6 mol S2O32-

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