A solution of 100 g/L acrylamide in methanol is polymerized at 25°C-with 0.1 mol/L isobutyryl peroxide whose half life is 9.0 h at this temperature and efficiency in methanol is 0.3. For acrylamide, k/k = 22 L mol-1 s- at 25° Cand termination is by coupling alone. (a) What is the initial steady state rate of polymerization ? (b) How much polymer has been made in the first 10 min of reaction in 1 L of solution ? (Ans. (a) 0.37 g L-l s-; (b) 89.4 g L-

Elements Of Electromagnetics
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6.2 A solution of 100 g/L acrylamide in methanol is polymerized at 25°C-with 0.1 mol/L
isobutyryl peroxide whose half life is 9.0 h at this temperature and efficiency in
methanol is 0.3. For acrylamide, klk = 22 L mol-1 s- at 25°Cand termination
is by coupling alone. (a) What is the initial steady state rate of polymerization ? (b)
How much polymer has been made in the first 10 min of reaction in 1 L of solution ?
[Ans. (a) 0.37 g L-1s-; (b) 89.4 g L-]
%3!
Transcribed Image Text:6.2 A solution of 100 g/L acrylamide in methanol is polymerized at 25°C-with 0.1 mol/L isobutyryl peroxide whose half life is 9.0 h at this temperature and efficiency in methanol is 0.3. For acrylamide, klk = 22 L mol-1 s- at 25°Cand termination is by coupling alone. (a) What is the initial steady state rate of polymerization ? (b) How much polymer has been made in the first 10 min of reaction in 1 L of solution ? [Ans. (a) 0.37 g L-1s-; (b) 89.4 g L-] %3!
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