A solution contains 0.10 M Sr(NO) and 0.20 M Bi(NO₂). When solid Na AsO is added to the solution a precipitation forms. What is the maximum concentration of AsO ³ just before the first salt precipitates? Ksp of Sr₂(AsO₂)₂ = 4.29 x 10-1⁹ and BIASO = 4.43 x 10-1⁰ 4

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A solution contains 0.10 M Sr(NO₃)₂ and 0.20 M Bi(NO₃)₃. When solid Na₃AsO₄ is added to the solution a precipitation forms. What is the maximum concentration of AsO₄³⁻ just before the first salt precipitates? 

Ksp of Sr₃(AsO₄)₂ = 4.29 x 10⁻¹⁹ and BiAsO₄ = 4.43 x 10⁻¹⁰
Transcribed Image Text:A solution contains 0.10 M Sr(NO₃)₂ and 0.20 M Bi(NO₃)₃. When solid Na₃AsO₄ is added to the solution a precipitation forms. What is the maximum concentration of AsO₄³⁻ just before the first salt precipitates? Ksp of Sr₃(AsO₄)₂ = 4.29 x 10⁻¹⁹ and BiAsO₄ = 4.43 x 10⁻¹⁰
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The question is based on the concept of solubility product principle. It states that when a weak electrolyte is dissolved in water it partially dissociates.  Only a small quantity of salt is dissolved and it quickly attains equilibrium and becomes saturated.

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