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(a) Since singlet oxygen is a high energy state, the formation of a diradical seems plausible: =o* Propose a sequence of steps for this diradical reacting with limonene and explain why the major product, which is obtained (Scheme 1), đoes not support this reaction mechanism

(a) Since singlet oxygen is a high energy state, the formation of a diradical seems plausible: =o* Propose a sequence of steps for this diradical reacting with limonene and explain why the major product, which is obtained (Scheme 1), đoes not support this reaction mechanism

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction between singlet oxygen and limonene (below) is often used to characterize the behaviour of singlet oxygen as an electrophile rather than an initiator for a free radical mechanism. HOO Limonene Scheme 1 (a) Since singlet oxygen is a high energy state, the formation of a diradical seems plausible: 0=0* Propose a sequence of steps for this diradical reacting with limonene and explain why the major product, which is obtained (Scheme 1), does not support this reaction mechanism
Transcribed Image Text:The reaction between singlet oxygen and limonene (below) is often used to characterize the behaviour of singlet oxygen as an electrophile rather than an initiator for a free radical mechanism. HOO Limonene Scheme 1 (a) Since singlet oxygen is a high energy state, the formation of a diradical seems plausible: 0=0* Propose a sequence of steps for this diradical reacting with limonene and explain why the major product, which is obtained (Scheme 1), does not support this reaction mechanism
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