A shortcut to finding optical isomers is to see if the complexhas a plane of symmetry—a plane passing through the metal atom such that every atom on one side of the plane is matched byan identical one at the same distance from the plane on the otherside. Any planar complex has a plane of symmetry, since allatoms lie in one plane. Use this approach to determine whetherthese exist as optical isomers: (a) [Zn(NH₃)₂Cl₂] (tetrahedral);(b) [Pt(en)₂]²⁻, (c) trans-[PtBr₄Cl₂]²⁺; (d) trans-[Co(en)₂F₂]⁺;(e)cis-[Co(en)₂F₂]⁺.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 105QRT
icon
Related questions
Question

A shortcut to finding optical isomers is to see if the complexhas a plane of symmetry—a plane passing through the metal atom such that every atom on one side of the plane is matched byan identical one at the same distance from the plane on the otherside. Any planar complex has a plane of symmetry, since allatoms lie in one plane. Use this approach to determine whetherthese exist as optical isomers: (a) [Zn(NH₃)₂Cl₂] (tetrahedral);(b) [Pt(en)₂]²⁻, (c) trans-[PtBr₄Cl₂]²⁺; (d) trans-[Co(en)₂F₂]⁺;(e)cis-[Co(en)₂F₂]⁺.

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning