A saturated-liquid mixture of 70 mol% benzene and 30 mol% toluene, whose relative volatility is  2.5, is to be distilled at 1 atm to produce a distillate of 80 mol% benzene. Three procedures,  described below, are under consideration. For each procedure, calculate and tabulate: (a) moles of  distillate per 100 moles of feed, (b) moles of total vapor generated per mole of distillate, and (c)  mol% benzene in the bottoms. (d) for each part, construct a y-x diagram. On this, indicate the  composition of the overhead product, the reflux, and the composition of the bottoms.   Continuous distillation in a column containing one equilibrium plate. The feed is sent to  the direct-heated still, from which residue is withdrawn continuously. The vapors from the  plate enter the top of a helically coiled partial condenser that discharges into a trap. The  liquid from the trap is returned to the plate, while the uncondensed vapor is condensed to  form a distillate containing 80 mol% benzene. The molar ratio of reflux to product is 0.5

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A saturated-liquid mixture of 70 mol% benzene and 30 mol% toluene, whose relative volatility is 
2.5, is to be distilled at 1 atm to produce a distillate of 80 mol% benzene. Three procedures, 
described below, are under consideration. For each procedure, calculate and tabulate: (a) moles of 
distillate per 100 moles of feed, (b) moles of total vapor generated per mole of distillate, and (c) 
mol% benzene in the bottoms. (d) for each part, construct a y-x diagram. On this, indicate the 
composition of the overhead product, the reflux, and the composition of the bottoms.

 

Continuous distillation in a column containing one equilibrium plate. The feed is sent to 
the direct-heated still, from which residue is withdrawn continuously. The vapors from the 
plate enter the top of a helically coiled partial condenser that discharges into a trap. The 
liquid from the trap is returned to the plate, while the uncondensed vapor is condensed to 
form a distillate containing 80 mol% benzene. The molar ratio of reflux to product is 0.5

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