A reaction A--B is studies at two temperatures. Use the data here to determine Ea. Report your answer in J/mol to 3 significant figures. T(deg C). 277 627 k (M/s) 0.282 0.291

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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QUESTION 1
A reaction A--B is studies at two temperatures. Use the data here to determine its
Ea.
Report your answer in J/mol to 3 significant figures.
I(deg C).
277
627
k (M/s)
0.282
0.291
Transcribed Image Text:QUESTION 1 A reaction A--B is studies at two temperatures. Use the data here to determine its Ea. Report your answer in J/mol to 3 significant figures. I(deg C). 277 627 k (M/s) 0.282 0.291
Expert Solution
Arrhenius relationship between rate constants and temperatures:

ln (k2 / k1) = -Ea / R [ 1/T2 - 1/T1 ]
From the given data,
k1 = 0.282 M/s   ;  T1 = 277oC = 277+273.15 = 550.15 K
k2 =0.291 M/s    ;  T2 = 627oC = 627+273.15 = 900.15 K
R = 8.3144 J K-1mol-1 

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