A polymer sample was analysed by differential scanning calorimetry and the thermogram shown in the figure below was obtained. Highlight and describe the key thermal transitions occurring in this sample.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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5.
(a) A polymer sample was analysed by differential scanning calorimetry
and the thermogram shown in the figure below was obtained.
Highlight and describe the key thermal transitions occurring in this
sample.
^
2
EXOTHERMIC
(b) From the reactivity ratio data for the free-radical copolymerisations
shown below, state what class of polymer is produced from these
reactions and justify your answer.
Reaction Monomer 1
1
Styrene
Styrene
Methyl
Methacrylate
Ethylene
3
50
Temperature
4
Monomer 2
Methyl
Methacrylate
Vinyl
acetate
Vinyl
chloride
Vinyl
acetate
Temp./°C r₁ 12
60
60
100
68
130
0.52 0.46
55 0.01
10 0.1
0.97 1.02
Transcribed Image Text:5. (a) A polymer sample was analysed by differential scanning calorimetry and the thermogram shown in the figure below was obtained. Highlight and describe the key thermal transitions occurring in this sample. ^ 2 EXOTHERMIC (b) From the reactivity ratio data for the free-radical copolymerisations shown below, state what class of polymer is produced from these reactions and justify your answer. Reaction Monomer 1 1 Styrene Styrene Methyl Methacrylate Ethylene 3 50 Temperature 4 Monomer 2 Methyl Methacrylate Vinyl acetate Vinyl chloride Vinyl acetate Temp./°C r₁ 12 60 60 100 68 130 0.52 0.46 55 0.01 10 0.1 0.97 1.02
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