A polymer sample was analysed by differential scanning calorimetry and the thermogram shown in the figure below was obtained. Highlight and describe the key thermal transitions occurring in this sample.
A polymer sample was analysed by differential scanning calorimetry and the thermogram shown in the figure below was obtained. Highlight and describe the key thermal transitions occurring in this sample.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:5.
(a) A polymer sample was analysed by differential scanning calorimetry
and the thermogram shown in the figure below was obtained.
Highlight and describe the key thermal transitions occurring in this
sample.
^
2
EXOTHERMIC
(b) From the reactivity ratio data for the free-radical copolymerisations
shown below, state what class of polymer is produced from these
reactions and justify your answer.
Reaction Monomer 1
1
Styrene
Styrene
Methyl
Methacrylate
Ethylene
3
50
Temperature
4
Monomer 2
Methyl
Methacrylate
Vinyl
acetate
Vinyl
chloride
Vinyl
acetate
Temp./°C r₁ 12
60
60
100
68
130
0.52 0.46
55 0.01
10 0.1
0.97 1.02
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