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(a) Please derive the Clapeyron equation and the Clausius-Clapeyron equation. clearly state all assumptions. (b) Diamond is metastable at atmospheric pressures and normal temperature. If the molar volume of diamond is smaller than that of the graphite, please draw the Gibbs free energy curves for diamond and graphite as a function of pressure at a constant temperature.

(a) Please derive the Clapeyron equation and the Clausius-Clapeyron equation. clearly state all assumptions. (b) Diamond is metastable at atmospheric pressures and normal temperature. If the molar volume of diamond is smaller than that of the graphite, please draw the Gibbs free energy curves for diamond and graphite as a function of pressure at a constant temperature.

Physical Chemistry
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter18: More Statistical Thermodynamics
Section: Chapter Questions
Problem 18.54E: In Chapters 17 and 18 we have derived expressions for the absolute amounts of the energies H and G....
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(a) Please derive the Clapeyron equation and the Clausius-Clapeyron equation. clearly state all assumptions. (b) Diamond is metastable at atmospheric pressures and normal temperature. If the molar volume of diamond is smaller than that of the graphite, please draw the Gibbs free energy curves for diamond and graphite as a function of pressure at a constant temperature.
Transcribed Image Text:(a) Please derive the Clapeyron equation and the Clausius-Clapeyron equation. clearly state all assumptions. (b) Diamond is metastable at atmospheric pressures and normal temperature. If the molar volume of diamond is smaller than that of the graphite, please draw the Gibbs free energy curves for diamond and graphite as a function of pressure at a constant temperature.
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