A pH probe/meter uses the following equations: Ecell = L + 0.0592 log a1 = L - 0.0592 pH Where L = L1 + EAg/AgCI + Easy= constants  L1 = - 0.0592 log a2 a1  = activity of analyte  solution                    a2  = activity of internal solution  Questions: How will measured pH value  be affected vs “real” pH if the temperature of the sample is 30C when pH was measured?  How will measured pH value be affected vs “real” pH if HCl in pH electrode, became 0.15M instead of 0.1M?  How pH value will be affected vs “real” pH if the glass of the pH electrode is not fully hydrated?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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A pH probe/meter uses the following equations:

Ecell = L + 0.0592 log a1 = L - 0.0592 pH

Where L = L1 + EAg/AgCI + Easy= constants 

L1 = - 0.0592 log a2

a= activity of analyte  solution                   

a= activity of internal solution 

Questions:

  1. How will measured pH value  be affected vs “real” pH if the temperature of the sample is 30C when pH was measured?
  2.  How will measured pH value be affected vs “real” pH if HCl in pH electrode, became 0.15M instead of 0.1M?

  3.  How pH value will be affected vs “real” pH if the glass of the pH electrode is not fully hydrated?

Please answer all questions and provide a brief explanation

 

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