A mixture of 0.04289 mol of C2H4, 0.08501 mol of N2, 0.02401 mol of NH3, and 0.05848 mol of C6H6 is placed in a 1.0-L steel pressure vessel at 1258 K. The following equilibrium is established: 3 C2H4(g) + 1 N2(g)  2 NH3(g) + 1 C6H6(g) At equilibrium 0.005819 mol of NH3 is found in the reaction mixture. (a) Calculate the equilibrium partial pressures of C2H4, N2, NH3, and C6H6.

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A mixture of 0.04289 mol of C2H4, 0.08501 mol of N2, 0.02401 mol of NH3, and 0.05848 mol of C6H6 is placed in a 1.0-L steel pressure vessel at 1258 K. The following equilibrium is established:

3 C2H4(g) + 1 N2(g)  2 NH3(g) + 1 C6H6(g)

At equilibrium 0.005819 mol of NH3 is found in the reaction mixture.





(a) Calculate the equilibrium partial pressures of C2H4, N2, NH3, and C6H6.


Peq(C2H4) =  .

Peq(N2) =  .

Peq(NH3) =  .

Peq(C6H6) =  .



(b) Calculate KP for this reaction.


KP =  .

Expert Solution
Step 1

The given chemical reaction is as follows:

3 C2H4(g) + 1 N2(g) -----------> 2 NH3(g) + 1 C6H6(g).............................(1).

The initial concentrations of the equilibrium species are,

[C2H4(g)]=moles of C2H4Volume in Liters= 0.04289 mol1 L= 0.04289 M.

[N2(g)]=moles of N2Volume in Liters=0.08501 mol 1 L= 0.08501 M.

[NH3(g)]=moles of NH3Volume in Liters= 0.02401 mol 1 L= 0.02401 M.

[C6H6(g)]=moles of C6H6Volume in Liters= 0.05848 mol 1 L= 0.05848 M.

We can also say that moles and the concentrations are equal for simplified calculation.

 

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