A mixture of isobutylene ((CH:)2CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH:):CCI) is 3.45 at 500.0 K. (CH:):CCI(g) = (CH:):CCH2(g) + HCI(g) Based on the given values, fill in the ICE table to determine the partial pressures of all| reactants and products. 1 Complete the ICE table below. (CH:).CCI(g) (CH:):CCH:(g) HCI(g) Initial (bar) Change (bar) Equilibrium (bar) 5 RESET 1 0.400 0.600 0.200 +x -X Activate W -2х 2x 0.600 - x 0.400 - x 0.600 + x 0.400 + x 0.200 + x 0.200 - x Go to Settings 3.45

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### Equilibrium Constants and ICE Tables in Chemical Reactions

**Introduction to the Problem:**

A mixture of isobutylene \(((CH_3)_2CCH_2\), 0.400 bar partial pressure) and HCl (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant \( K \) for the gas-phase thermal decomposition of tert-butyl chloride \(((CH_3)_3CCl)\) is 3.45 at 500.0 K.

The reaction is as follows:
\[
(CH_3)_3CCl(g) \leftrightharpoons (CH_3)_2CCH_2(g) + HCl(g)
\]

**Objective:**

Based on the given values, fill in the ICE (Initial, Change, Equilibrium) table to determine the partial pressures of all reactants and products.

**ICE Table:**

|                          | \((CH_3)_3CCl(g)\) | \(\leftrightharpoons\) | \((CH_3)_2CCH_2(g)\) | +          | \(HCl(g)\)    |
|--------------------------|--------------------|------------------------|----------------------|------------|---------------|
| **Initial (bar)**        |                    |                        |                      |            |               |
| **Change (bar)**         |                    |                        |                      |            |               |
| **Equilibrium (bar)**    |                    |                        |                      |            |               |

**Instructions for ICE Table Completion:**

1. **Identify Initial Pressures:**
   - **(CH_3)_3CCl(g):** (To be determined)
   - **(CH_3)_2CCH_2(g):** 0.400 bar
   - **HCl(g):** 0.600 bar

2. **Determine Changes in Pressures:** Use \( x \) to represent the change.
   - **(CH_3)_3CCl(g):** -x
   - **(CH_3)_2CCH_2(g):** +x
   - **HCl(g):** +x

3. **Calculate Equilibrium Pressures:**
   - **(CH_3)_3CCl(g):** Initial - x
   - **(CH_3)_2CCH_2(g):** \( 0.
Transcribed Image Text:### Equilibrium Constants and ICE Tables in Chemical Reactions **Introduction to the Problem:** A mixture of isobutylene \(((CH_3)_2CCH_2\), 0.400 bar partial pressure) and HCl (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant \( K \) for the gas-phase thermal decomposition of tert-butyl chloride \(((CH_3)_3CCl)\) is 3.45 at 500.0 K. The reaction is as follows: \[ (CH_3)_3CCl(g) \leftrightharpoons (CH_3)_2CCH_2(g) + HCl(g) \] **Objective:** Based on the given values, fill in the ICE (Initial, Change, Equilibrium) table to determine the partial pressures of all reactants and products. **ICE Table:** | | \((CH_3)_3CCl(g)\) | \(\leftrightharpoons\) | \((CH_3)_2CCH_2(g)\) | + | \(HCl(g)\) | |--------------------------|--------------------|------------------------|----------------------|------------|---------------| | **Initial (bar)** | | | | | | | **Change (bar)** | | | | | | | **Equilibrium (bar)** | | | | | | **Instructions for ICE Table Completion:** 1. **Identify Initial Pressures:** - **(CH_3)_3CCl(g):** (To be determined) - **(CH_3)_2CCH_2(g):** 0.400 bar - **HCl(g):** 0.600 bar 2. **Determine Changes in Pressures:** Use \( x \) to represent the change. - **(CH_3)_3CCl(g):** -x - **(CH_3)_2CCH_2(g):** +x - **HCl(g):** +x 3. **Calculate Equilibrium Pressures:** - **(CH_3)_3CCl(g):** Initial - x - **(CH_3)_2CCH_2(g):** \( 0.
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