A mixture of isobutylene ((CH:)2CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH:):CCI) is 3.45 at 500.0 K. (CH:):CCI(g) = (CH:):CCH2(g) + HCI(g) Based on the given values, fill in the ICE table to determine the partial pressures of all| reactants and products. 1 Complete the ICE table below. (CH:).CCI(g) (CH:):CCH:(g) HCI(g) Initial (bar) Change (bar) Equilibrium (bar) 5 RESET 1 0.400 0.600 0.200 +x -X Activate W -2х 2x 0.600 - x 0.400 - x 0.600 + x 0.400 + x 0.200 + x 0.200 - x Go to Settings 3.45
A mixture of isobutylene ((CH:)2CCH2, 0.400 bar partial pressure) and HCI (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant K for the gas-phase thermal decomposition of tert-butyl chloride ((CH:):CCI) is 3.45 at 500.0 K. (CH:):CCI(g) = (CH:):CCH2(g) + HCI(g) Based on the given values, fill in the ICE table to determine the partial pressures of all| reactants and products. 1 Complete the ICE table below. (CH:).CCI(g) (CH:):CCH:(g) HCI(g) Initial (bar) Change (bar) Equilibrium (bar) 5 RESET 1 0.400 0.600 0.200 +x -X Activate W -2х 2x 0.600 - x 0.400 - x 0.600 + x 0.400 + x 0.200 + x 0.200 - x Go to Settings 3.45
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Equilibrium Constants and ICE Tables in Chemical Reactions
**Introduction to the Problem:**
A mixture of isobutylene \(((CH_3)_2CCH_2\), 0.400 bar partial pressure) and HCl (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant \( K \) for the gas-phase thermal decomposition of tert-butyl chloride \(((CH_3)_3CCl)\) is 3.45 at 500.0 K.
The reaction is as follows:
\[
(CH_3)_3CCl(g) \leftrightharpoons (CH_3)_2CCH_2(g) + HCl(g)
\]
**Objective:**
Based on the given values, fill in the ICE (Initial, Change, Equilibrium) table to determine the partial pressures of all reactants and products.
**ICE Table:**
| | \((CH_3)_3CCl(g)\) | \(\leftrightharpoons\) | \((CH_3)_2CCH_2(g)\) | + | \(HCl(g)\) |
|--------------------------|--------------------|------------------------|----------------------|------------|---------------|
| **Initial (bar)** | | | | | |
| **Change (bar)** | | | | | |
| **Equilibrium (bar)** | | | | | |
**Instructions for ICE Table Completion:**
1. **Identify Initial Pressures:**
- **(CH_3)_3CCl(g):** (To be determined)
- **(CH_3)_2CCH_2(g):** 0.400 bar
- **HCl(g):** 0.600 bar
2. **Determine Changes in Pressures:** Use \( x \) to represent the change.
- **(CH_3)_3CCl(g):** -x
- **(CH_3)_2CCH_2(g):** +x
- **HCl(g):** +x
3. **Calculate Equilibrium Pressures:**
- **(CH_3)_3CCl(g):** Initial - x
- **(CH_3)_2CCH_2(g):** \( 0.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1243504b-5612-4510-ba6c-7b5ec7c70d6e%2F168dd0de-ca89-44d9-abe3-552e2c100ffc%2Fga3rcrg_processed.png&w=3840&q=75)
Transcribed Image Text:### Equilibrium Constants and ICE Tables in Chemical Reactions
**Introduction to the Problem:**
A mixture of isobutylene \(((CH_3)_2CCH_2\), 0.400 bar partial pressure) and HCl (0.600 bar partial pressure) is heated at 500.0 K. The equilibrium constant \( K \) for the gas-phase thermal decomposition of tert-butyl chloride \(((CH_3)_3CCl)\) is 3.45 at 500.0 K.
The reaction is as follows:
\[
(CH_3)_3CCl(g) \leftrightharpoons (CH_3)_2CCH_2(g) + HCl(g)
\]
**Objective:**
Based on the given values, fill in the ICE (Initial, Change, Equilibrium) table to determine the partial pressures of all reactants and products.
**ICE Table:**
| | \((CH_3)_3CCl(g)\) | \(\leftrightharpoons\) | \((CH_3)_2CCH_2(g)\) | + | \(HCl(g)\) |
|--------------------------|--------------------|------------------------|----------------------|------------|---------------|
| **Initial (bar)** | | | | | |
| **Change (bar)** | | | | | |
| **Equilibrium (bar)** | | | | | |
**Instructions for ICE Table Completion:**
1. **Identify Initial Pressures:**
- **(CH_3)_3CCl(g):** (To be determined)
- **(CH_3)_2CCH_2(g):** 0.400 bar
- **HCl(g):** 0.600 bar
2. **Determine Changes in Pressures:** Use \( x \) to represent the change.
- **(CH_3)_3CCl(g):** -x
- **(CH_3)_2CCH_2(g):** +x
- **HCl(g):** +x
3. **Calculate Equilibrium Pressures:**
- **(CH_3)_3CCl(g):** Initial - x
- **(CH_3)_2CCH_2(g):** \( 0.
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