A mass spectrometer is a tool used to determine accurately the mass of individual ionized atoms or molecules, or to separate atoms or molecules that have similar but slightly different masses. For example, you can deduce the age of a small sample of cloth from an ancient tomb, by using a mass spectrometer to determine the relative abundances of carbon-14 (whose nucleus contains 6 protons and 8 neutrons) and carbon-12 (the most common isotope, whose nuceus contains 6 protons and 6 neutrons). In organic material the ratio of 1"C to 12c depends on how old the material is, which is the basis for "carbon-14 dating." C is continually produced in the upper atmosphere by nuclear reactions caused by "cosmic rays" (high-energy charged particles from outer space, mainly protons), and C is radioactive with a half-ife of 5700 years. When a cotton plant is growing, some of the COz it extracts from the air to build tissue contains "C which has diffused down from the upper atmosphere. But after the cotton has been harvested there is no further intake of 4c from the air, and the cosmic rays that create C in the upper atmosphere can't penetrate the atmosphere and reach the cloth. So the amount of 14C in cotton cloth continualy decreases with time, while the amount of non-radioactive 1c remains constant. Here is a particular kind of mass spectrometer (see the figure). Carbon from the sample is ionized in the lon source at the left. The resulting singly ionized 1c* and c* ions have negligibly small initial velocities (and can be considered to be at rest). They are accelerated through the potential difference Av. They then enter a region where the magnetic field has a foxed magnitude 8= 0.18 T. The lons pass through electric defiection plates that are 1 cm apart and have a potential difference AV2 that is adjusted so that the electric deflection and the magnetic deflection cancel each other for a particular isotope: one isotope goes straight through, and the other isotope is deflected and misses the entrance to the next section of the spectrometer. The distance from the entrance to the fixed ion detector is a distance of w- 22 cm. There are controls that let you vary the accelerating potential AV and the deflection potential AVz in order that only c* or "c* ions go all the way through the system and reach the detector. You count each kind of ion for fixed times and thus determine the relative abundances. The various defiections insure that you count only the desired type of ion for a particular setting of the two voltages. Accclerating plates AV. detector Deflection plates AV Oher isctope s deflected throurhout this region (a) Which accelerating plate is positive? left O right Which deflection plate is positive? top O bottom What is the direction of the magnetic field inside the spectrometer? O out of page into page (b) Determine the appropriate numerical values of AV; and Av, for c. Carry out your intermediate calculations algebraically, so that you can use the algebraic results in the next part. AV - AVz - (c) Determine the appropriate numerical values of AV, and AV for c. AV:

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Please do part b and c

Mass spectrometer
A mass spectrometer is a tool used to determine accurately the mass
individual ionized atoms or molecules, or to separate atoms or molecules that have similar but slightly different masses. For example, you can deduce the age of a small sample of cloth from an ancient tomb, by using a mass
spectrometer to determine the relative abundances of carbon-14 (whose nucleus contains 6 protons and 8 neutrons) and carbon-12 (the most common isotope, whose nucleus contains 6 protons and 6 neutrons). In organic material the ratio of 14C to 12c depends on how old the material is, which is the basis
for "carbon-14 dating." 14C is continually produced in the upper atmosphere by nuclear reactions caused by "cosmic rays" (high-energy charged particles from outer space, mainly protons), and 14c is radioactive with a half-life of 5700 years. When a cotton plant is growing, some of the COz it extracts from
the air to build tissue contains 14C which has diffused down from the upper atmosphere. But after the cotton has been harvested there is no further intake of 14C from the air, and the cosmic rays that create 14C in the upper atmosphere can't penetrate the atmosphere and reach the cloth. So the amount of
14C in cotton cloth continually decreases with time, while the amount of non-radioactive 12c remains constant.
Here is a particular kind of mass spectrometer (see the figure). Carbon from the sample is ionized in the ion source at the left. The resulting singly ionized 12c* and 14c+ ions have negligibly small initial velocities (and can be considered to be at rest). They are accelerated through the potential difference AV1
They then enter a region where the magnetic field has a fixed magnitude B = 0.18 T. The ions pass through electric deflection plates that are 1 cm apart and have a potential difference AV2 that is adjusted so that the electric deflection and the magnetic deflection cancel each other for a particular isotope: one
isotope goes straight through, and the other isotope is deflected and misses the entrance to the next section of the spectrometer. The distance from the entrance to the fixed ion detector is a distance of w = 22 cm. There are controls that let you vary the accelerating potential AV, and the deflection potential
AVz in order that only 12c+ or 14c+ ions go all the way through the system and reach the detector. You count each kind of ion for fixed times and thus determine the relative abundances. The various deflections insure that you count only the desired type of ion for a particular setting of the two voltages.
Accelerating
plates; AVi
lon
detector
Deflection
plates; AV
lon!
Other isotope
is deflected
nonzero B
throughout this region
(a) Which accelerating plate is positive?
O left
O right
Which deflection plate is positive?
O top
O bottom
What is the direction of the magnetic field inside the spectrometer?
O out of page
O into page
(b) Determine the appropriate numerical values of AV1 and AV2 for 12C. Carry out your intermediate calculations algebraically, so that you can use the algebraic results in the next part.
AV. =
V
AV2 -
(c) Determine the appropriate numerical values of AV1 and AV2 for 14c.
AV =
AV2 =
Transcribed Image Text:Mass spectrometer A mass spectrometer is a tool used to determine accurately the mass individual ionized atoms or molecules, or to separate atoms or molecules that have similar but slightly different masses. For example, you can deduce the age of a small sample of cloth from an ancient tomb, by using a mass spectrometer to determine the relative abundances of carbon-14 (whose nucleus contains 6 protons and 8 neutrons) and carbon-12 (the most common isotope, whose nucleus contains 6 protons and 6 neutrons). In organic material the ratio of 14C to 12c depends on how old the material is, which is the basis for "carbon-14 dating." 14C is continually produced in the upper atmosphere by nuclear reactions caused by "cosmic rays" (high-energy charged particles from outer space, mainly protons), and 14c is radioactive with a half-life of 5700 years. When a cotton plant is growing, some of the COz it extracts from the air to build tissue contains 14C which has diffused down from the upper atmosphere. But after the cotton has been harvested there is no further intake of 14C from the air, and the cosmic rays that create 14C in the upper atmosphere can't penetrate the atmosphere and reach the cloth. So the amount of 14C in cotton cloth continually decreases with time, while the amount of non-radioactive 12c remains constant. Here is a particular kind of mass spectrometer (see the figure). Carbon from the sample is ionized in the ion source at the left. The resulting singly ionized 12c* and 14c+ ions have negligibly small initial velocities (and can be considered to be at rest). They are accelerated through the potential difference AV1 They then enter a region where the magnetic field has a fixed magnitude B = 0.18 T. The ions pass through electric deflection plates that are 1 cm apart and have a potential difference AV2 that is adjusted so that the electric deflection and the magnetic deflection cancel each other for a particular isotope: one isotope goes straight through, and the other isotope is deflected and misses the entrance to the next section of the spectrometer. The distance from the entrance to the fixed ion detector is a distance of w = 22 cm. There are controls that let you vary the accelerating potential AV, and the deflection potential AVz in order that only 12c+ or 14c+ ions go all the way through the system and reach the detector. You count each kind of ion for fixed times and thus determine the relative abundances. The various deflections insure that you count only the desired type of ion for a particular setting of the two voltages. Accelerating plates; AVi lon detector Deflection plates; AV lon! Other isotope is deflected nonzero B throughout this region (a) Which accelerating plate is positive? O left O right Which deflection plate is positive? O top O bottom What is the direction of the magnetic field inside the spectrometer? O out of page O into page (b) Determine the appropriate numerical values of AV1 and AV2 for 12C. Carry out your intermediate calculations algebraically, so that you can use the algebraic results in the next part. AV. = V AV2 - (c) Determine the appropriate numerical values of AV1 and AV2 for 14c. AV = AV2 =
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