А J KMnOд, ОН, heat B Br2 Br2 H29 1) ВНз C 2) H2О2, ОН" HBr, H2O2 Оз, Zn 1) Hg(ОАc)2, СH3ОН 2) NaBH4 CH212, Zn m-СРВА OsO4 G E F

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
### Chemical Reaction Pathways of an Epoxide

This diagram displays various reaction pathways of a cyclohexene oxide, illustrating the different products that can result from various reagents and reaction conditions.

#### Pathway A:
- **Reagents:** KMnO₄, OH⁻, heat
- **Product:** The double bond is oxidized, leading to cleavage of the double bond and formation of diol.

#### Pathway B:
- **Reagents:** Br₂ 
- **Product:** The double bond reacts with bromine to form a dibromo compound.

#### Pathway C:
- **Reagents:** HBr, H₂O₂
- **Product:** The double bond undergoes anti-Markovnikov addition in the presence of HBr and H₂O₂, resulting in the addition of HBr across the double bond.

#### Pathway D:
- **Reagents:** 1) Hg(OAc)₂, CH₃OH; 2) NaBH₄
- **Product:** This is an oxymercuration-demercuration reaction that adds an -OCH₃ group and an H across the double bond. 

#### Pathway E:
- **Reagents:** m-CPBA
- **Product:** The double bond reacts with meta-chloroperoxybenzoic acid to form an epoxide.

#### Pathway F:
- **Reagents:** OsO₄
- **Product:** The double bond reacts with osmium tetroxide to form a cis-diol.

#### Pathway G:
- **Reagents:** CH₂I₂, Zn
- **Product:** The double bond reacts to form a cyclopropane ring.

#### Pathway H:
- **Reagents:** O₃, Zn
- **Product:** The double bond is cleaved by ozonolysis to form aldehyde or ketone fragments.

#### Pathway I:
- **Reagents:** 1) BH₃; 2) H₂O₂, OH⁻ 
- **Product:** The double bond is converted into an alcohol with anti-Markovnikov orientation through hydroboration-oxidation.

#### Pathway J:
- **Reagent:** Br₂, H₂O
- **Product:** Bromohydrin is formed when the double bond reacts with bromine in an aqueous solution.

Each of these pathways demonstrates a distinct type of chemical reaction, showcasing the versatility of organic synthesis methods
Transcribed Image Text:### Chemical Reaction Pathways of an Epoxide This diagram displays various reaction pathways of a cyclohexene oxide, illustrating the different products that can result from various reagents and reaction conditions. #### Pathway A: - **Reagents:** KMnO₄, OH⁻, heat - **Product:** The double bond is oxidized, leading to cleavage of the double bond and formation of diol. #### Pathway B: - **Reagents:** Br₂ - **Product:** The double bond reacts with bromine to form a dibromo compound. #### Pathway C: - **Reagents:** HBr, H₂O₂ - **Product:** The double bond undergoes anti-Markovnikov addition in the presence of HBr and H₂O₂, resulting in the addition of HBr across the double bond. #### Pathway D: - **Reagents:** 1) Hg(OAc)₂, CH₃OH; 2) NaBH₄ - **Product:** This is an oxymercuration-demercuration reaction that adds an -OCH₃ group and an H across the double bond. #### Pathway E: - **Reagents:** m-CPBA - **Product:** The double bond reacts with meta-chloroperoxybenzoic acid to form an epoxide. #### Pathway F: - **Reagents:** OsO₄ - **Product:** The double bond reacts with osmium tetroxide to form a cis-diol. #### Pathway G: - **Reagents:** CH₂I₂, Zn - **Product:** The double bond reacts to form a cyclopropane ring. #### Pathway H: - **Reagents:** O₃, Zn - **Product:** The double bond is cleaved by ozonolysis to form aldehyde or ketone fragments. #### Pathway I: - **Reagents:** 1) BH₃; 2) H₂O₂, OH⁻ - **Product:** The double bond is converted into an alcohol with anti-Markovnikov orientation through hydroboration-oxidation. #### Pathway J: - **Reagent:** Br₂, H₂O - **Product:** Bromohydrin is formed when the double bond reacts with bromine in an aqueous solution. Each of these pathways demonstrates a distinct type of chemical reaction, showcasing the versatility of organic synthesis methods
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Thermodynamics
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY