a-Hydroxyketones and a-hydroxyaldehydes are also oxidized by treatment with periodic acid. 1. Н, О H. 2. HIO, ОН (гасemie) It is not the a-hydroxyketone or aldehyde, however, that undergoes reaction with periodic acid, but the hydrate formed by addition of water to the carbonyl group of the a-hydroxyketone or aldehyde. Write a mechanism for the oxidation of this a-hydroxyaldehyde by HIO,.

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Chapter1: Chemical Foundations
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a-Hydroxyketones and a-hydroxyaldehydes are also oxidized by treatment
with periodic acid.
1. Н, О
H.
2. HIO,
ОН
(гасemie)
It is not the a-hydroxyketone or aldehyde, however, that undergoes reaction
with periodic acid, but the hydrate formed by addition of water to the carbonyl
group of the a-hydroxyketone or aldehyde. Write a mechanism for the
oxidation of this a-hydroxyaldehyde by HIO,.
Transcribed Image Text:a-Hydroxyketones and a-hydroxyaldehydes are also oxidized by treatment with periodic acid. 1. Н, О H. 2. HIO, ОН (гасemie) It is not the a-hydroxyketone or aldehyde, however, that undergoes reaction with periodic acid, but the hydrate formed by addition of water to the carbonyl group of the a-hydroxyketone or aldehyde. Write a mechanism for the oxidation of this a-hydroxyaldehyde by HIO,.
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