Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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[References]
H2O
OH
TsO.
DMSO
ÓH
Chrysanthemyl tosylate
Artemesia alcohol
Yomogi alcohol
Chrysanthemic acid occurs as a mixture of esters in flowers of the chrysanthemum (pyrethrum) family. Reduction of chrysanthemic acid to its alcohol,
followed by conversion of the alcohol to its tosylate, gives chrysanthemyl tosylate.
Solvolysis of the tosylate gives a mixture of artemesia and yomogi alcohols.
Draw curved arrows to show the movement of electrons in this step of the reaction mechanism.
Arrow-pushing Instructions
:A
H-A
TH.
Transcribed Image Text:[References] H2O OH TsO. DMSO ÓH Chrysanthemyl tosylate Artemesia alcohol Yomogi alcohol Chrysanthemic acid occurs as a mixture of esters in flowers of the chrysanthemum (pyrethrum) family. Reduction of chrysanthemic acid to its alcohol, followed by conversion of the alcohol to its tosylate, gives chrysanthemyl tosylate. Solvolysis of the tosylate gives a mixture of artemesia and yomogi alcohols. Draw curved arrows to show the movement of electrons in this step of the reaction mechanism. Arrow-pushing Instructions :A H-A TH.
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