A group of chemistry students determined the titratable acidity of two brands of tetrapack juice. Titratable acidity is a measure of the total acid concentration in a food sample. Titratable acidity in fruit juices is commonly expressed in terms of milligrams (mg) of hydrous citric acid (H3CitH20, MM: 210.14 g/mol) per mL solution. Initially, they have prepared the sodium hydroxide solution and standardized it with oxalic acid dihydrate (H2C204-2H20; MM:126.02 g/mol; 99.5% purity) up to the faint pink endpoint of phenolphthalein. The volumes of the duplicate trial of the standardization were summarized in the table. In the sample analysis, 5.00mL each of tetra pack juice was diluted with 50.0 mL of distilled water and titrated up to an endpoint of 8.2 using a pH meter. Consider the tables below and answer the following questions. Table 1. Standardization of the NaOH titrant grams of primary standard Volume NaOH used (mL) 0.2490 39.4 0.2510 39.5 Table 2. Titration of the samples with the standardized titrant. Volume Readout of Burette (mL, NAOH) Sample Initial Final Brand X 0.00 1.90 Brand Y 2.10 3.60 What is the molarity of the titrant? M Note: it requires 3 moles of hydroxide to titrate 1 mole of citric acid Calculate the molarity of citric acid in both of the samples? Band X sample. Brand Y sample M

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A group of chemistry students determined the titratable acidity of two brands of tetrapack juice. Titratable
acidity is a measure of the total acid concentration in a food sample. Titratable acidity in fruit juices is commonly
expressed in terms of milligrams (mg) of hydrous citric acid (H3CitH20, MM: 210.14 g/mol) per mL solution.
Initially, they have prepared the sodium hydroxide solution and standardized it with oxalic acid dihydrate
(H2C204 2H20; MM:126.02 g/mol; 99.5% purity) up to the faint pink endpoint of phenolphthalein. The volumes of
the duplicate trial of the standardization were summarized in the table. In the sample analysis, 5.00ML each of
tetra pack juice was diluted with 50.0 mL of distilled water and titrated up to an endpoint of 8.2 using a pH meter.
Consider the tables below and answer the following questions.
Table 1. Standardization of the NaOH titrant
grams of primary standard
Volume NaOH used (mL)
0.2490
39.4
0.2510
39.5
Table 2. Titration of the samples with the standardized titrant.
Volume Readout of Burette (mL, NaOH)
Sample
Initial
Final
Brand X
0.00
1.90
Brand Y
2.10
3.60
What is the molarity of the titrant?
M
Note: it requires 3 moles of hydroxide to titrate 1 mole of citric acid
Calculate the molarity of citric acid in both of the samples?
Band X sample.
Brand Y sample
M
Transcribed Image Text:A group of chemistry students determined the titratable acidity of two brands of tetrapack juice. Titratable acidity is a measure of the total acid concentration in a food sample. Titratable acidity in fruit juices is commonly expressed in terms of milligrams (mg) of hydrous citric acid (H3CitH20, MM: 210.14 g/mol) per mL solution. Initially, they have prepared the sodium hydroxide solution and standardized it with oxalic acid dihydrate (H2C204 2H20; MM:126.02 g/mol; 99.5% purity) up to the faint pink endpoint of phenolphthalein. The volumes of the duplicate trial of the standardization were summarized in the table. In the sample analysis, 5.00ML each of tetra pack juice was diluted with 50.0 mL of distilled water and titrated up to an endpoint of 8.2 using a pH meter. Consider the tables below and answer the following questions. Table 1. Standardization of the NaOH titrant grams of primary standard Volume NaOH used (mL) 0.2490 39.4 0.2510 39.5 Table 2. Titration of the samples with the standardized titrant. Volume Readout of Burette (mL, NaOH) Sample Initial Final Brand X 0.00 1.90 Brand Y 2.10 3.60 What is the molarity of the titrant? M Note: it requires 3 moles of hydroxide to titrate 1 mole of citric acid Calculate the molarity of citric acid in both of the samples? Band X sample. Brand Y sample M
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