A chemist has a bottle that contains 250 mL of a 0.787 M solution of aluminum chloride. What are the concentrations of chloride ions and of aluminum ions in the bottle?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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**Educational Content: Determining Ion Concentrations in a Solution**

**Problem Statement:**
A chemist has a bottle that contains 250 mL of a 0.787 M solution of aluminum chloride. What are the concentrations of chloride ions and of aluminum ions in the bottle?

**Options:**
- A. \([Cl^-] = 0.60 \, \text{mol/L}, \, [Al^{3+}] = 0.20 \, \text{mol/L}\)
- B. \([Cl^-] = 0.787 \, \text{mol/L}, \, [Al^{3+}] = 0.787 \, \text{mol/L}\)
- C. \([Cl^-] = 0.787 \, \text{mol/L}, \, [Al^{3+}] = 2.36 \, \text{mol/L}\)
- D. \([Cl^-] = 0.0031 \, \text{mol/L}, \, [Al^{3+}] = 0.0031 \, \text{mol/L}\)
- E. \([Cl^-] = 2.36 \, \text{mol/L}, \, [Al^{3+}] = 0.787 \, \text{mol/L}\)

**Analysis of Problem:**
Aluminum chloride, \(\text{AlCl}_3\), dissociates into one aluminum ion (\(Al^{3+}\)) and three chloride ions (\(Cl^-\)) in solution. For every mole of \(\text{AlCl}_3\) that dissociates, one mole of \(Al^{3+}\) ions and three moles of \(Cl^-\) ions are produced.

Given:
- The concentration of the \(\text{AlCl}_3\) solution is 0.787 M.

**Calculation:**
- The concentration of \(Al^{3+}\) ions is equal to the concentration of \(\text{AlCl}_3\), which is 0.787 M.
- The concentration of \(Cl^-\) ions is three times the concentration of \(\text{AlCl}_3\), which is \(3 \times 0.787 \, \text{M} = 2.361 \, \text{M}\).

**Correct Answer:**
- E. \
Transcribed Image Text:**Educational Content: Determining Ion Concentrations in a Solution** **Problem Statement:** A chemist has a bottle that contains 250 mL of a 0.787 M solution of aluminum chloride. What are the concentrations of chloride ions and of aluminum ions in the bottle? **Options:** - A. \([Cl^-] = 0.60 \, \text{mol/L}, \, [Al^{3+}] = 0.20 \, \text{mol/L}\) - B. \([Cl^-] = 0.787 \, \text{mol/L}, \, [Al^{3+}] = 0.787 \, \text{mol/L}\) - C. \([Cl^-] = 0.787 \, \text{mol/L}, \, [Al^{3+}] = 2.36 \, \text{mol/L}\) - D. \([Cl^-] = 0.0031 \, \text{mol/L}, \, [Al^{3+}] = 0.0031 \, \text{mol/L}\) - E. \([Cl^-] = 2.36 \, \text{mol/L}, \, [Al^{3+}] = 0.787 \, \text{mol/L}\) **Analysis of Problem:** Aluminum chloride, \(\text{AlCl}_3\), dissociates into one aluminum ion (\(Al^{3+}\)) and three chloride ions (\(Cl^-\)) in solution. For every mole of \(\text{AlCl}_3\) that dissociates, one mole of \(Al^{3+}\) ions and three moles of \(Cl^-\) ions are produced. Given: - The concentration of the \(\text{AlCl}_3\) solution is 0.787 M. **Calculation:** - The concentration of \(Al^{3+}\) ions is equal to the concentration of \(\text{AlCl}_3\), which is 0.787 M. - The concentration of \(Cl^-\) ions is three times the concentration of \(\text{AlCl}_3\), which is \(3 \times 0.787 \, \text{M} = 2.361 \, \text{M}\). **Correct Answer:** - E. \
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