A chemist has a 50.0 mL sample of 0.010 M Na₂C₂O4 at 25 °C (solution A, oxalate ion = C₂O4²- ). An aqueous solution of Ca(NO3)2 with a volume of 50.0 mL (solution B) is added to solution A, at the same temperature. Above what minimum concentration must Ca(NO3)2 in solution B be, prior to mixing, to cause CaC₂O4 to precipitate given that for CaC2O4, Ksp = 2.7 x 10-9 at 25 °C? Enter your answer with two significant figures, without units, and in millimolarity (mM) where: millimolarity = (molarity)(1000)

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Chapter1: Chemical Foundations
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### Problem Statement:

A chemist has a 50.0 mL sample of 0.010 M Na₂C₂O₄ at 25 °C (solution A, oxalate ion = C₂O₄²⁻). An aqueous solution of Ca(NO₃)₂ with a volume of 50.0 mL (solution B) is added to solution A, at the same temperature.

Above what minimum concentration must Ca(NO₃)₂ in solution B be, *prior to mixing*, to cause CaC₂O₄ to precipitate given that for CaC₂O₄, Kₛₚ = 2.7 × 10⁻⁹ at 25 °C?

### Instructions:

Enter your answer with two **significant figures**, without units, and in millimolarity (mM) where:

\[ \text{millimolarity} = (\text{molarity})(1000) \]

### Possible Answers:

- 0.001 (with margin: 0)
- 0.0011 (with margin: 0)
Transcribed Image Text:### Problem Statement: A chemist has a 50.0 mL sample of 0.010 M Na₂C₂O₄ at 25 °C (solution A, oxalate ion = C₂O₄²⁻). An aqueous solution of Ca(NO₃)₂ with a volume of 50.0 mL (solution B) is added to solution A, at the same temperature. Above what minimum concentration must Ca(NO₃)₂ in solution B be, *prior to mixing*, to cause CaC₂O₄ to precipitate given that for CaC₂O₄, Kₛₚ = 2.7 × 10⁻⁹ at 25 °C? ### Instructions: Enter your answer with two **significant figures**, without units, and in millimolarity (mM) where: \[ \text{millimolarity} = (\text{molarity})(1000) \] ### Possible Answers: - 0.001 (with margin: 0) - 0.0011 (with margin: 0)
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