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A certain substance has a heat of vaporization of 34.65 kJ/mol. At what Kelvin temperature will the vapor pressure be 6.00 times higher than it was at 333 K? T = K

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter8: Molecules And Materials

Section: Chapter Questions

Problem 8.83PAE

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Question

A certain substance has a heat of vaporization of 34.65 kJ/mol. At what Kelvin temperature will the vapor pressure be 6.00 times
higher than it was at 333 K?
T =
K

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The molar heat of fusion of sodium metal is 2.60 kJ/mol, whereas its heat of vaporization is 97.0 kJ/mol. a. Why is the heat of vaporization so much larger than the heat of fusion? b. What quantity of heat would be needed to melt 1.00 g sodium at its normal melting point? c. What quantity of heat would be needed to vaporize 1.00 g sodium at its normal boiling point? d. What quantity of heat would be evolved if 1.00 g sodium vapor condensed at its normal boiling point?
Why are steam burns so much worse than water burns even if the H2O is at the same temperature for both phases? Hint: Consider the heat of vaporization of water.
Carbon tetrachloride, CCl4, has a vapor pressure of 213 torr at 40.C and 836 torr at 80.C. What is the normal boiling point of CCl4?
White phosphorus, P4, is normally a white, waxy solid melting at 44C to a colorless liquid. The liquid has a vapor pressure of 400.0 mmHg at 251.0C and 760.0 mmHg at 280.0C. What is the heat of vaporization of this substance?
Diethyl ether (CH3CH2OCH2CH3) was one of the first chemicals used as an anesthetic. At 34.6C, diethyl ether has a vapor pressure of 760. torr, and at 17.9C, it has a vapor pressure of 400. torr. What is the H of vaporization for diethyl ether?
Which of the following do you expect to be molecular solids? a silicon tetrachloride, SiCl4 b lithium bromide, LiBr c sodium fluoride, NaF d bromine chloride, BrCl
Follow the step-wise process outlined in Problem 31 to calculate the amount of heat involved in condensing 100.00 g of benzene gas (C6H6) at 80.00C to liquid benzene at 25.00C. Use Tables 8.1 and 8.2 for the specific heat, boiling point, and heat of vaporization of benzene.
Calculate the quantity of heating required to convert the water in four ice cubes (60.1 g each) from H2O(s) at 0 °C to H2O(g) at 100. °C. The enthalpy of fusion of ice is 333 J/g and the enthalpy of vaporization of liquid water is 2260 J/g.
The phase diagram for water over a relative narrow pressure and temperature range is given in Figure 9.19. A phase diagram over a considerably wider range of temperature and pressure (kbar) is given nearby. This phase diagram illustrates the polymorphism of ice, the existence of a solid in more than one form. In this case, Roman numerals are used to designate each polymorphic form. For example, Ice I, ordinary ice, is the form that exists under ordinary pressures. The other forms exist only at higher pressures, in some cases extremely high pressure such as Ice VII and Ice VIII. Using the phase diagram, give the approximate P and T conditions at the triple point for Ice III, Ice V, and liquid water. Determine the approximate temperature and pressure for the triple point for Ices VI, VII, and VIII. What is anomalously different about the fusion curves for Ice VI and Ice VII compared to that of Ice I? What phases exist at 8 kbar and 20 °C? At a constant temperature of −10 °C, start at 3 kbar and increase the pressure to 7 kbar. Identify all the phase changes that occur sequentially as these conditions change. Explain why there is no triple point for the combination of Ice VII, Ice VIII, and liquid water.
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Water at 0C was placed in a dish inside a vessel maintained at low pressure by a vacuum pump. After a quantity of water had evaporated, the remainder froze. If 9.31 g of ice at 0C was obtained, how much liquid water must have evaporated? The heat of fusion of water is 6.01 kJ/mol and its heat of vaporization is 44.9 kJ/mol at 0C.

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