A certain reaction has an activation energy of 30.07 kJ/mol. At what Kelvin temperature will the reaction proceed 7.50 times faster than it did at 353 K? K T =
A certain reaction has an activation energy of 30.07 kJ/mol. At what Kelvin temperature will the reaction proceed 7.50 times faster than it did at 353 K? K T =
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Problem Statement
A certain reaction has an activation energy of 30.07 kJ/mol. At what Kelvin temperature will the reaction proceed 7.50 times faster than it did at 353 K?
**Equation Placeholder:**
\[ T = \_\_\_\_\_\_ \, \text{K} \]
### Explanation
In this problem, we are asked to find the temperature at which a reaction proceeds 7.50 times faster than it does at 353 K, given the activation energy of 30.07 kJ/mol. This requires understanding the relationship between the rate of a reaction, temperature, and activation energy, often modeled by the Arrhenius equation:
\[ k = A \cdot e^{-\frac{E_a}{RT}} \]
Where:
- \( k \) is the rate constant.
- \( A \) is the pre-exponential factor (frequency of collisions).
- \( E_a \) is the activation energy.
- \( R \) is the universal gas constant (8.314 J/mol·K).
- \( T \) is the temperature in Kelvin.
### Objective
Determine the temperature \( T \) such that the rate constant \( k \) at this temperature is 7.50 times greater than the rate constant at 353 K. The calculations involve using the modified form of the Arrhenius equation to solve for \( T \).
### Additional Steps
1. **Understand the Relationship**: The rate of reaction depends exponentially on temperature. Increasing the temperature generally increases the rate.
2. **Perform Calculations**: Use the relationship \(\frac{k_2}{k_1} = 7.50\) to solve for the new temperature \( T \).
### Conclusion
Once the temperature is calculated using the Arrhenius equation and appropriate transformations for the given rate increase, it can be plugged into the equation placeholder.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F7fb0039e-8ad4-434f-994c-a091a87f4676%2F04a7fc21-68da-4e6f-b20f-4036cab69a47%2Furpdfaxo_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Problem Statement
A certain reaction has an activation energy of 30.07 kJ/mol. At what Kelvin temperature will the reaction proceed 7.50 times faster than it did at 353 K?
**Equation Placeholder:**
\[ T = \_\_\_\_\_\_ \, \text{K} \]
### Explanation
In this problem, we are asked to find the temperature at which a reaction proceeds 7.50 times faster than it does at 353 K, given the activation energy of 30.07 kJ/mol. This requires understanding the relationship between the rate of a reaction, temperature, and activation energy, often modeled by the Arrhenius equation:
\[ k = A \cdot e^{-\frac{E_a}{RT}} \]
Where:
- \( k \) is the rate constant.
- \( A \) is the pre-exponential factor (frequency of collisions).
- \( E_a \) is the activation energy.
- \( R \) is the universal gas constant (8.314 J/mol·K).
- \( T \) is the temperature in Kelvin.
### Objective
Determine the temperature \( T \) such that the rate constant \( k \) at this temperature is 7.50 times greater than the rate constant at 353 K. The calculations involve using the modified form of the Arrhenius equation to solve for \( T \).
### Additional Steps
1. **Understand the Relationship**: The rate of reaction depends exponentially on temperature. Increasing the temperature generally increases the rate.
2. **Perform Calculations**: Use the relationship \(\frac{k_2}{k_1} = 7.50\) to solve for the new temperature \( T \).
### Conclusion
Once the temperature is calculated using the Arrhenius equation and appropriate transformations for the given rate increase, it can be plugged into the equation placeholder.
Expert Solution
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Step 1
Arrhenius equation:
If we know the value of the rate constant at two different temperatures, and the activation energy we can calculate the temperature of the reaction by using the Arrhenius equation. The Arrhenius equation is given by:
where k2 = rate constant at the T2 temperature
k1 = rate constant at T1
k2 = 7.50 k1
Ea = activation energy = 30.07 kJ/mol = 30.07x103 J/mol
R = gas constant = 8.314 J/K.mol
T1 = 353 K
T2 = to be calculate
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