A certain catalyst undergoes sintering overtime, causing its catalytic activity to decrease according to the following deactivation kinetic model: kaa³ The deactivation constant (ka, day-¹) follows an Arrhenius type temperature - dependency as shown: T'd da dt -1500 ka = 50e T dimit falls 050/ below.

Introduction to Chemical Engineering Thermodynamics
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ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A certain catalyst undergoes sintering overtime, causing its catalytic activity
to decrease according to the following deactivation kinetic model:
ra =
da
dt
ka
= kaa³
The deactivation constant (ka, day¯¹) follows an Arrhenius type temperature
- dependency as shown:
-1500
= 50e T
The catalyst is to be replaced when its activity falls to 95% below its original
activity. If the reactor is operated T = 300 K, how long should this catalyst be
used?
Transcribed Image Text:A certain catalyst undergoes sintering overtime, causing its catalytic activity to decrease according to the following deactivation kinetic model: ra = da dt ka = kaa³ The deactivation constant (ka, day¯¹) follows an Arrhenius type temperature - dependency as shown: -1500 = 50e T The catalyst is to be replaced when its activity falls to 95% below its original activity. If the reactor is operated T = 300 K, how long should this catalyst be used?
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