(a) Calculate the fugacity of CO at 50 bar and 400 bar, if the following data are applicable at 273 K.P, bar25501002004008001000Z0.98900.97920.97411.01961.24821.80572.0819(b) Using the values of Z at 50 and 400 bar, calculate the van der Waals constants for CO. From these determine the fugacities at these pressures and compare the results with the previous ones.

(a) Write the expression for fugacity as follows: lnfP = Z-1 .......(1) Case(1): At…

Answered: (a) Calculate the fugacity of CO at 50…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

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(a) Calculate the fugacity of CO at 50 bar and 400 bar, if the following data are applicable at 273 K.

P, bar	25	50	100	200	400	800	1000
Z	0.9890	0.9792	0.9741	1.0196	1.2482	1.8057	2.0819

(b) Using the values of Z at 50 and 400 bar, calculate the van der Waals constants for CO. From these determine the fugacities at these pressures and compare the results with the previous ones.

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