(a) (c) (d) CH3 CH2 Br CI H CH3 + CH₂ CH₂. CH3 DBN "bulky base" Br CH CH3 CH₂CH3 CH3 + CH3OH O + NaSH + Na OCH3 25°C SN1 El SN2 E2 SN1 SN2 El E2 SN1 SN2 E1 SN1 E1 E2 SN2 E2
(a) (c) (d) CH3 CH2 Br CI H CH3 + CH₂ CH₂. CH3 DBN "bulky base" Br CH CH3 CH₂CH3 CH3 + CH3OH O + NaSH + Na OCH3 25°C SN1 El SN2 E2 SN1 SN2 El E2 SN1 SN2 E1 SN1 E1 E2 SN2 E2
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For each of the following reactions, circle the mechanism(s) you would expect to see and provide the major product(s). Write NR for no reaction, if you don’t expect any reaction.
![The image presents a series of chemical reactions, illustrating mechanisms and reaction pathways involving nucleophilic substitutions (S_N1 and S_N2) and elimination reactions (E1 and E2).
**Diagram (a):**
- Reactants: A cyclohexyl chloride compound with a bulky base, DBN (1,5-diazabicyclo[4.3.0]non-5-ene).
- Products: Not explicitly shown, but the boxed mechanisms to the right indicate the possible pathways: S_N1, S_N2, E1, or E2.
**Diagram (b):**
- Reactants: A linear alkyl iodide compound with sodium hydrogen sulfide (NaSH).
- Products: Not explicitly shown, but the boxed mechanisms suggest pathways via S_N1, S_N2, E1, or E2.
**Diagram (c):**
- Reactants: A cycloalkyl bromide with sodium methoxide (Na^+ OCH_3^-).
- Products: Similar to the others, potential reaction pathways include S_N1, S_N2, E1, or E2 as indicated in the box.
**Diagram (d):**
- Reactants: An alkyl bromide with methanol (CH_3OH) at 25°C.
- Products: Again, potential mechanisms include S_N1, S_N2, E1, or E2 as shown in the box.
Each reaction scheme displays the reactants followed by an arrow leading to a box. Each box categorizes the potential reaction pathways, demonstrating the flexibility in organic mechanisms and the influence of factors like the nature of the base, leaving groups, and reaction conditions.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffd14f466-2175-4b26-80f9-e0672840c669%2Fe58859d3-0f7b-40ab-9831-fb25a469a1a4%2Fnfp0hvnr_processed.png&w=3840&q=75)
Transcribed Image Text:The image presents a series of chemical reactions, illustrating mechanisms and reaction pathways involving nucleophilic substitutions (S_N1 and S_N2) and elimination reactions (E1 and E2).
**Diagram (a):**
- Reactants: A cyclohexyl chloride compound with a bulky base, DBN (1,5-diazabicyclo[4.3.0]non-5-ene).
- Products: Not explicitly shown, but the boxed mechanisms to the right indicate the possible pathways: S_N1, S_N2, E1, or E2.
**Diagram (b):**
- Reactants: A linear alkyl iodide compound with sodium hydrogen sulfide (NaSH).
- Products: Not explicitly shown, but the boxed mechanisms suggest pathways via S_N1, S_N2, E1, or E2.
**Diagram (c):**
- Reactants: A cycloalkyl bromide with sodium methoxide (Na^+ OCH_3^-).
- Products: Similar to the others, potential reaction pathways include S_N1, S_N2, E1, or E2 as indicated in the box.
**Diagram (d):**
- Reactants: An alkyl bromide with methanol (CH_3OH) at 25°C.
- Products: Again, potential mechanisms include S_N1, S_N2, E1, or E2 as shown in the box.
Each reaction scheme displays the reactants followed by an arrow leading to a box. Each box categorizes the potential reaction pathways, demonstrating the flexibility in organic mechanisms and the influence of factors like the nature of the base, leaving groups, and reaction conditions.
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