A buffer is prepared by mixing 204 mL of 0.452 M HCl and 0.50 L of 0.400 M sodium acetate. (See Appendix) a) What is the pH? b) How many grams of KOH must be added to 0.500 L of the buffer to change the pH by 0.15 units?

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5. A buffer is prepared by mixing 204 mL of 0.452 M HCl and 0.50 L of 0.400 M sodium acetate.
(See Appendix)
a) What is the pH?
b) How many grams of KOH must be added to 0.500 L of the buffer to change the pH by 0.15 units?

Table of Acids with Ka and pKa values
Acid
НА
A
Ка
pKa
H;O*
Hydronium ion
Iodic
Oxalic (1)
Sulfurous (1)
Sulfuric (2)
HO
IO;
HC2O4
HSO;
1
0.0
1.6 x 101
5.9 x 10
1.54 x 102
1.2 x 102
1.1 x 10
7.52 x 10*
5.0 x 10
1.4 x 10
8.4 x 10
7.2 x 10*
4.0 x 10
1.77 x 10*
1.38 x 10*
7.9 x 10
6.46 x 10
6.4 x 10
1.9 x 10
1.8 x 10°
1.76 x 10
1.34 x 10
5.6 x 10
4.0 x 10*
4.3 x 10"
1.02 x 10
8/9.3 x 10*
1.0 x 10-//9.1 x 10-8
6.23 x 10
3.5/3.0 x 10*
2х 10%
6.17 x 1010
5.8 x 1010
5.6 х 1010
1.6х 1010
4.8 x 10"
2 x 10"
| 6.0 x 10-1º/3.0 x 10-12
2.4 x 1012
1.6 x 10*12
4.8/2.2 x 1013
1.0 x 10
HIO3
0.80
H»C2O4
1.23
H;SO3
HSO;
HC1O,
H;PO4
H3ASO4
CH,CICOOH
H;C¿H;O7
HF
HNO,
НСООН
HCH3H§O3
H¿C¿HO6
C3HsCOOH
1.81
1.92
Chlorous
ClO,
H,PO,
1.96
Phosphoric (1)
Arsenic (1)
Chloroacetic
Citric (1)
Hydrofluoric
Nitrous
Formic
2.12
2.30
CH,CICOO
H,C¢H;O;¯
F
2.85
3.08
3.14
NO
3.39
HCOO
3.75
Lactic
CH;HsO;
3.86
Ascorbic (1)
Benzoic
Охalic (2)
Hydrazoic
Citric (2)
4.10
C¢H;COO"
4.19
C,0,
4.19
HN3
H,C¿H5O7¯
CH;COOH
CH;CH,COOH
C;H¾NH
N3
4.72
HC¿H;O;²
4.74
Acetic
CH;COO"
CH;CH,COO
C;H¾N
4.75
Propionic
Pyridinium ion
Citric (3)
Carbonic (1)
Sulfurous (2)
Arsenic (2)
Hydrosulfuric
Phosphoric (2)
Нурochlorous
Нуpobromous
Hydrocyanic
Boric (1)
Ammonium ion
Phenol
Carbonic (2)
Нурoiodous
Arsenic (3)
4.87
5.25
3-
5.40
6.37
H,CO}
HSO;
H;AsOq¨
H2S
HCO;
SO
HASO
6.91
7.10/7.03
HS
04.רוך
H,PO4
HCIO
НРО
Clo
7.21
7.46/7.53
HBrO
BrO"
8.70
HCN
CN
9.21
9.23
H;BO3
NH,"
C¢H;OH
HCO;
H;BO;
NH3
9.25
9.80
10.32
HIO
IO
10.70
Aso,
HO;
3-
HASO,²
9.22/11.53
Hydrogen peroxide
Ascorbic (2)
Phosphoric (3)
11.62
HC,H&O6¯
НРО
H;O
11.80
PO,
12.32/12.66
Water
OH
14.0
Transcribed Image Text:Table of Acids with Ka and pKa values Acid НА A Ка pKa H;O* Hydronium ion Iodic Oxalic (1) Sulfurous (1) Sulfuric (2) HO IO; HC2O4 HSO; 1 0.0 1.6 x 101 5.9 x 10 1.54 x 102 1.2 x 102 1.1 x 10 7.52 x 10* 5.0 x 10 1.4 x 10 8.4 x 10 7.2 x 10* 4.0 x 10 1.77 x 10* 1.38 x 10* 7.9 x 10 6.46 x 10 6.4 x 10 1.9 x 10 1.8 x 10° 1.76 x 10 1.34 x 10 5.6 x 10 4.0 x 10* 4.3 x 10" 1.02 x 10 8/9.3 x 10* 1.0 x 10-//9.1 x 10-8 6.23 x 10 3.5/3.0 x 10* 2х 10% 6.17 x 1010 5.8 x 1010 5.6 х 1010 1.6х 1010 4.8 x 10" 2 x 10" | 6.0 x 10-1º/3.0 x 10-12 2.4 x 1012 1.6 x 10*12 4.8/2.2 x 1013 1.0 x 10 HIO3 0.80 H»C2O4 1.23 H;SO3 HSO; HC1O, H;PO4 H3ASO4 CH,CICOOH H;C¿H;O7 HF HNO, НСООН HCH3H§O3 H¿C¿HO6 C3HsCOOH 1.81 1.92 Chlorous ClO, H,PO, 1.96 Phosphoric (1) Arsenic (1) Chloroacetic Citric (1) Hydrofluoric Nitrous Formic 2.12 2.30 CH,CICOO H,C¢H;O;¯ F 2.85 3.08 3.14 NO 3.39 HCOO 3.75 Lactic CH;HsO; 3.86 Ascorbic (1) Benzoic Охalic (2) Hydrazoic Citric (2) 4.10 C¢H;COO" 4.19 C,0, 4.19 HN3 H,C¿H5O7¯ CH;COOH CH;CH,COOH C;H¾NH N3 4.72 HC¿H;O;² 4.74 Acetic CH;COO" CH;CH,COO C;H¾N 4.75 Propionic Pyridinium ion Citric (3) Carbonic (1) Sulfurous (2) Arsenic (2) Hydrosulfuric Phosphoric (2) Нурochlorous Нуpobromous Hydrocyanic Boric (1) Ammonium ion Phenol Carbonic (2) Нурoiodous Arsenic (3) 4.87 5.25 3- 5.40 6.37 H,CO} HSO; H;AsOq¨ H2S HCO; SO HASO 6.91 7.10/7.03 HS 04.רוך H,PO4 HCIO НРО Clo 7.21 7.46/7.53 HBrO BrO" 8.70 HCN CN 9.21 9.23 H;BO3 NH," C¢H;OH HCO; H;BO; NH3 9.25 9.80 10.32 HIO IO 10.70 Aso, HO; 3- HASO,² 9.22/11.53 Hydrogen peroxide Ascorbic (2) Phosphoric (3) 11.62 HC,H&O6¯ НРО H;O 11.80 PO, 12.32/12.66 Water OH 14.0
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