2.4. (a) A block of copper at a pressure of 1 atm (approximately 100 kPa) and a tem-perature of 5°C is kept at constant volume. If the temperature is raised to 10°C,what will be the final pressure?(b) If the vessel holding the block of copper has a negligibly small thermal expan-sivity and can withstand a maximum pressure of 1000 atm, what is the highesttemperature to which the system may be raised?(Note: The volume expansivity ß and isothermal compressibility k are not alwayslisted in handbooks of data. However, ß is three times the linear expansion coefficienta, and k is the reciprocal of the bulk modulus B. For this problem, assume that thevolume expansivity and isothermal compressibility remain practically constant withinthe temperature range of 0 to 20°C at the values of 4.95 × 10-5 K-1 and6.17 x 10-12 Pa-!, respectively.)

Given that:β=4.95×10-5 K-1K=6.17×10-12 Pa-1a) Pi=100 kPaTi=5°CTf=10°CPf=?b) P2=1000 atmT2=?

Answered: A block of copper at a pressure of 1…

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