I need help on questions 2-3 2. Do the following synthesis:(a) Benzene to 1-t-butyl-3-ethylbenzene(b) Benzene to m-bromobenzoic acid(c) Benzene to Benzene-1,3-dicarboxylic acid(d) Benzene to p-t-butylbenzoic acid(e) Benzene to 1,3-dipropylbenzene(f) Benzene to p-nitrobenzoic acid(g) Benzene to p-bromobenzaldehyde(h) Acetopheneone to 1,3-diethylbenzene3. What is the main product for each of the following reactions?(a) p-Methylanisole + CH3CH2CH2CI, AlCl3 --------> ?(b) Toluene + Br2, light, then CH3CH2COCI, AIC13 --------> ?(c) Acetophenone + CH3CH2CI, AICI3, then Br2, FeBr3 -----> ?(d) Styrene + CH3CH2COCI, AICI3, then Br2, Fe -----> ?(e) Benzene + 1-chloro-2,2-dimethylpropane, AlCl3 -----> ?(f) Benzene + 3-phenyl-1-propene, H2SO4, heat -------> ?(g) Toluene + 1-phenyl-3,3-dimethyl-2-butanol, H2SO4, heat ------> ?(h) Benzene + CH3COCI, AlICl3 then 2-chlorobutane, AlCl3 -----> ?

Since you have posted question with sub-parts , we are entitled to answer the first three sub-parts…

Answered: (a) Benzene to 1-t-butyl-3-ethylbenzene…

Science

Chemistry

(a) Benzene to 1-t-butyl-3-ethylbenzene (b) Benzene to m-bromobenzoic acid (c) Benzene to Benzene-1,3-dicarboxylic acid

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.SE: Something Extra

Problem 28VC

See similar textbooks

Related questions

Q: synthesis could take more than one step. OH OCH3 1. OH 2. Predicting the expected major product.…

A: The question is based on the concept of organic reaction We have to convert the reactant into…

Q: KOH(aq) is classified as a + base. The reaction equation with water would utilize which of the…

Q: A mixture containing table salt, sand and NH4Cl is placed into a beaker and weighed. The entire…

A: (2) Given that - Mass of entire content containing table salt (NaCl) , sand , Ammonium Chloride…

Q: seconds created alo Is C,H,Cl being created or destroyed by the chemical O destroyed reaction?…

A: Here from the Concentration of C4H9Cl versus time graph, we have to determine the instantaneous…

Q: Please help with questions 1-3. Very confused

A: Here a weak base is being reacted with a strong acid.So together they will form a basic buffer.

Q: AHvap (NO2) = +32.0 kJ/mol at its normal boiling point, 21°C. 1. Consider the enthalpy of condensing…

A: ∆Hvap = +32 kJ / mol Temperature (T) = 21℃

Q: a. How many carbon atoms are in the sam b. How many hydrogen atoms are in the s c. How many oxygen…

Q: 2. Do your observations support the principle that mass is conserved in a chemical reaction, that…

A: “Since you have asked multiple question, we will solve the first (Q2) question for you. If you want…

Q: Could I get help with questions 1-3?

A: Approach- Draw the graphs - [A] Vs T 2. ln[A] Vs T 3) 1 / [A] vs T Out of three graphs. the…

Q: A student performs the experiment and acquires a mass of 9.25g for a 10mL addition of 12

A: Part 2: Mass of water = 9.25 g Volume of water = 10 mL To determine: Percent error for this trial

Q: 3. 4. i) volume of water in cylinder #1 (25 mL to start), ii) volume of water in #2, iii)…

A: Answer-3 Chemical equilibrium is called as dynamic equilibrium, because it is the state of the…

Q: 2. A buffer solution of volume 0.500 L contains 1.68 g NH3 and 4.05 g (NH);SOu. a) What is the pH of…

A: “Since you have asked multiple questions, we will solve the first question [Q2] for you. If you want…

Q: Safety: While these are household items that you could easily purchase at the store, please…

A: #Q.1: Your calculation for #Q.1 is correct which is 7.95 g

Q: The stronger the IMFs the higher the boiling point (a) Draw structures for the two molecules, name…

A: Since you have asked multiple questions we will answer the first one for you. To get the remaining…

Q: 1. A golf course intends to place pesticide on the course. The directions call for 15.00 pounds of…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: 2. Confirmatory tests for the various ions are often colorful. Identify the confirmatory…

A: We have find out the confirmatory test for various ions and reagents for separations.

Q: , then you can help me on question 1.

A: Molarity of KMnO4 solution is 0.1M. Trial-1: Initial burette level = 0.45 mL Final burette level=…

Q: QUESTION 2 How many moles of gas are in each flask? (Hint 1 atm =760mmHg)? OA0.15 moles O B. 107.7…

A: Given, Volume of gas = 3.0 L Temperature = 25°C = 25+273 = 298 K Pressure = 878 mm Hg Conversion…

Q: a. Are the bonds between carbon and oxygen polar or nonpolar? lecule polar or nonpolar? (Hint:…

A: Answer

Q: 3. If 20.05 mL of 0.105 M HCI are titrated with 17.35 mL of an NaOH solution. a. Write the balanced…

A: Acid–base titration : It is a quantitative method method of determining the concentration of an acid…

Q: 3.1 Atomic Mass 1) Chlorine exists as a mixture of 2 major isotopes, Chlorine-35 and Chlorine-37.…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: 2. Given the reactions (1), (2) and (3) below determine the standard enthalpy of formation (AH,) of…

Q: 8. A piece of unknown metal with a mass of 5.19g is heated to 100.00°C and dropped into 10.0mL of…

A: Heat released or absorbed (Q) = m . s . ∆T Where, m = mass of substance, s = specific heat of…

Q: 2) Did your sample contain Ag+ ions? 3) What test was most critical in determining if your sample…

A: A common method used to identify the ions in a mixture is quantitative analysis. In this method the…

Q: Which, if any, of the following are weak acids? (Circle your choice[s].) HC2H3O2, HCI, NaC2H3O2,…

A: “Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: 201 Le Chatelier's Principle in Iron Thiocyanate Equilibrium Prelab Name. _Section , Le Chatelier's…

A: In a chemical reaction, the chemical balance is the condition in which both the reactants and the…

Q: 2. Write the atomic symbol ( zA) for the following a) the element with 8 protons and 18 neutrons b)…

A: 1. Z= atomic number= no. of proton in an element A= mass number= Z+ no. of neutron As per the…

Q: 1) Determine the moles of KMnO4 required for each trial. 41.43 mL 0.45 mL = 40.98 mL of KMnO4 moles…

A: Given that, Molarity of KMnO4 solution is 0.1 M. For trial 1: Initial burette reading = 0.45 mL…

Q: Pre-Lab Study Questions 7 1. Why does a sodium street lamp give off a yellow color, whereas a neon…

A: The color of the light depends on the element you are contacting. In contact with energy, the…

Q: 1) A lab technician makes three successive 5.0 mL-to-50.0 mL dilutions (like was described in your…

A: To solve the question-1, we have to understand the successive dilution that are employed here----…

Q: 2) Find the energy required to ionize a ground state hydrogen atom. That is, what is the energy…

A: As per bartleyby guidelines i answered only first question so please don't mind. Thanks in advance.

Q: 1. Fill in the following table. [H₂O*] (M) 5.9x10² [OH] (M) 3.6x10³ PH 3.9 РОН 6.5

Q: Rank the elements or compounds in the table below in decreasing order of their boiling points. That…

Q: Page 14018 3) The second electron affinity of oxygen is positive, making the oxide not likely to…

A: Since you have asked multiple question, we will solve the first question for you.If you want any…

Q: 4. Cell membranes consist of an arrangement of phospholipids called the where the outer and inner…

A: Please find your solution below : 4. Cell membranes consists of an arrangement of phospholipids…

Q: 2 Mg 02 2 Mgo 1. How many moles of O2 are needed to completely react with 6 moles of Mg? 2. How many…

A: " Since you have posted a question with multiple sub-parts , we will solve first three sub-parts for…

Q: In the calorimeter experiment, you mixed 50 mL of 1.0 M NaOH with 50 mL of approximately 1.0 M HCI.…

A: A positive ΔHº value represents an addition of energy from the reaction (and from the surroundings),…

Q: Help solve 1,2,3,4,5.

A: 1.To find the standard Gibbs free energy change (ΔGrxn∘) for the ionization of acetic acid…

Q: Consider a balloon that will expand without any restriction until it pops. If the balloon 12) can…

A: Note: As per the guidelines solution of 1st challenge question has been made. For the expert…

Q: Briefly summarize the experiment Rutherford used to develop his model. Use diagrams. Draw a picture…

A: Rutherford directed a beam of alpha particles on a thin foil of gold, and the foil was surrounded by…

Q: Write the net ionic equation for the chemical reaction shown. Include physical states. HCIO,(aq) +…

A: Since HClO2 is a weak acid, it will not dissociate completely into its corresponding ions. Also, H2O…

Q: Please solution to questions 3&4

A: Answer 3 :- B option is correct. 2 NaCl Answer 4 :- C option is correct. 0.201g of Hydrogen

Q: 2) Calculate the concentrations of the FeSCN²" solutions you prepared in Part 1 and, using these…

A: #2: Calculation for [FeSCN2+(aq)] of the solutions in part-1: In part-1, we have taken a very small…

Q: 4) Circle the benzene analog that undergoes Friedel-Crafts alkylation/acylation most rapidly? -COOH…

A: 4. EDGroups increase the reactivity of benzen ring towards electrophile. Therefore anisole reacts…

Concept explainers

Analytical Tools

Analytical tools or analysis tools help one to get into a conclusion or results from the data collected. Analytical tools can be applied for simple data sets and also in the case of big data analytics.

Question

I need help on questions 2-3

2. Do the following synthesis:
(a) Benzene to 1-t-butyl-3-ethylbenzene
(b) Benzene to m-bromobenzoic acid
(c) Benzene to Benzene-1,3-dicarboxylic acid
(d) Benzene to p-t-butylbenzoic acid
(e) Benzene to 1,3-dipropylbenzene
(f) Benzene to p-nitrobenzoic acid
(g) Benzene to p-bromobenzaldehyde
(h) Acetopheneone to 1,3-diethylbenzene
3. What is the main product for each of the following reactions?
(a) p-Methylanisole + CH3CH2CH2CI, AlCl3 --------> ?
(b) Toluene + Br2, light, then CH3CH2COCI, AIC13 --------> ?
(c) Acetophenone + CH3CH2CI, AICI3, then Br2, FeBr3 -----> ?
(d) Styrene + CH3CH2COCI, AICI3, then Br2, Fe -----> ?
(e) Benzene + 1-chloro-2,2-dimethylpropane, AlCl3 -----> ?
(f) Benzene + 3-phenyl-1-propene, H2SO4, heat -------> ?
(g) Toluene + 1-phenyl-3,3-dimethyl-2-butanol, H2SO4, heat ------> ?
(h) Benzene + CH3COCI, AlICl3 then 2-chlorobutane, AlCl3 -----> ?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Do the reactions and he explains why.
(a) How will you convert:(i) Benzene to acetophenone (ii) Propanone to 2-Methylpropan-2-ol(b) Give reasons :(i) Electrophilic substitution in benzoic acid takes place at meta position.(ii) Carboxylic acids are higher boiling liquids than aldehydes, ketones and alcohols of comparable molecular masses.(iii) Propanal is more reactive than propanone in nucleophilic addition reactions.
The hydrocarbon fluorene was treated with potassium t-butoxide in an acid-base reaction, giving the fluorenide anion and t-butyl alcohol. (a) Which way does the equilibrium lie, and by how much? b) What is the proportion of the fluorenide anion to fluorene? (c) Why is fluorene so highly acidic, considering the pKa of an average alkane is above 50?
4. identify the structure of A and B in the following synthetic scheme: Write out complete reactions for each step, showing the structure of all reactants and products. (a) cyclohexanol +Na2Cr2O7/H2SO4, H2O -------> A (b) A + Et2NH/H2SO4 ----->B
(c)Show step by step how to synthesize methoxybenzene from benzene.
(a) Which of the following will NOT produce a carboxylic acid or carboxylate ion? 1-butanol + H2CrO4 2-butene + O3/H2O2 butanal + PCC butanal + H2CrO4 (b) Which of the following will NOT produce a carboxylic acid or carboxylate ion? 1-butanol + H2CrO4 2-butene + O3/H2O2 butanal + PCC butanal + H2CrO4
How could you convert each of the following compounds into butanoic acid? Write each step showing all reagents. (a) 1-Butanol (b) 1-Bromobutane (c) 1-Butene
Need help with D, not C.
Give reasons for the following: (i) p-nitrophenol is more acidic than p-methylphenol. (ii) Bond length of C—O bond in phenol is shorter than that in methanol. (iii) (CH3)3C—Br on reaction with sodium methoxide (Na+ _OCH3) gives alkene as the main product and not an ether.
1. At what position and on what ring would you expect the following substances to undergo electrophilic substitution? (b) CH3 Br lel CH3 2. Rank the compounds in each group according to their reactivity toward electrophilic substitution. (a) Chlorobenzene, o-dichlorobenzene, benzene (b) p-Bromonitrobenzene, nitrobenzene, phenol (c) Fluorobenzene, benzaldehyde, 0-xylene (d) Benzonitrile, p-methylbenzonitrile, p-methoxybenzonitrile
Predict the product of the following reactions. (a) 1. NaOEt, EtOH, heat 2. H3O+ quench (b) Pho O O OEt OMe 1. NaOMe, MeOH, heat 2. H3O+ quench
4) Aromatic compounds are among the most abundant and versatile in nature. From a synthetic point of view, these compounds, despite their stabilities, are quite useful and can undergo reactions under special conditions and by specific mechanisms, such as the Electrophilic Aromatic Substitution (SAE) and the Nucleophilic Aromatic Substitution (SNAr). Based on this, please answer the following items: (b) How would you prepare the following compounds starting from benzene? Explain the second in a different way